ArticleNational science review2020
Shadow glass transition as a thermodynamic signature of β relaxation in hyper-quenched metallic glasses.
Article in National science review, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed, 91 citations in OpenAlex.
- Direct correspondence between liquid and glass polymorphism in densely packed metallic alloys.Nature communications · 2026Article
- Johari-Goldstein relaxation in quenched and irradiated chalcogenide glasses.Newton ((New York, N.Y.) · 2026Article
- Beyond geometry orders: uncovering bonding-heterogeneity-dominated structure-relaxation coupling in glasses.National science review · 2026Article
- Crossover of quasi-localized dynamics and diffusion in supercooled liquids.Nature physics · 2026Article
- Atomic-Level Structural Characteristics of β-Relaxation in Metallic Glasses.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Linking the pressure dependence of the structure and thermal stability to α- and β-relaxations in metallic glasses.Science advances · 2025Article
- Complexity of confined water vitrification and its glass transition temperature.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Size-dependent vitrification in metallic glasses.Nature communications · 2023Article
- 'Shadow' glass transition in glass.National science review · 2021Article
- Decoupling between calorimetric and dynamical glass transitions in high-entropy metallic glasses.Nature communications · 2021Article
- Physical Aging Behavior of a Glassy Polyether.Polymers · 2021Article
- Predicting orientation-dependent plastic susceptibility from static structure in amorphous solids via deep learning.Nature communications · 2021Article
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Authors and funding
4 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
One puzzling phenomenon in glass physics is the so-called 'shadow glass transition' which is an anomalous heat-absorbing process below the real glass transition and influences glass properties. However, it has yet to be entirely characterized, let alone fundamentally understood. Conventional calorimetry detects it in limited heating rates. Here, with the chip-based fast scanning calorimetry, we study the dynamics of the shadow glass transition over four orders of magnitude in heating rates for 24 different hyper-quenched metallic glasses. We present evidence that the shadow glass transition correlates with the secondary (β) relaxation: (i) The shadow glass transition and the β relaxation follow the same temperature-time dependence, and both merge with the primary relaxation at high temperature. (ii) The shadow glass transition is more obvious in glasses with pronounced β relaxation, and
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