Evidence map›Paper›PMID 34669254›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Macrocyclic Donor-Acceptor Dyads Composed of a Perylene Bisimide Dye Surrounded by Oligothiophene Bridges.

Kevin Bold, Matthias Stolte, Kazutaka Shoyama, Marco Holzapfel, Alexander Schmiedel, Christoph Lambert, Frank Würthner

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. 1D Fully spSmall (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Kevin BoldInstitut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Matthias StolteInstitut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Kazutaka ShoyamaInstitut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Marco HolzapfelInstitut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Alexander SchmiedelInstitut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Christoph LambertInstitut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Frank WürthnerInstitut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.ORCID http://orcid.org/0000-0001-7245-0471

Funding

Bayerisches Staatsministerium für Bildung und Kultus, Wissenschaft und Kunst
6 · The paper itself

Abstract

Two macrocyclic architectures comprising oligothiophene strands that connect the imide positions of a perylene bisimide (PBI) dye have been synthesized via a platinum-mediated cross-coupling strategy. The crystal structure of the double bridged PBI reveals all syn-arranged thiophene units that completely enclose the planar PBI chromophore via a 12-membered macrocycle. The target structures were characterized by steady-state UV/Vis absorption, fluorescence and transient absorption spectroscopy, as well as cyclic and differential pulse voltammetry. Both donor-acceptor dyads show ultrafast Förster Resonance Energy Transfer and photoinduced electron transfer, thereby leading to extremely low fluorescence quantum yields even in the lowest polarity cyclohexane solvent.

Indexed as

donor-acceptor dyadsmacrocyclesoligothiophenesperylene bisimidephotoinduced electron transfer

Identifiers

PMID34669254
PMCPMC9299635

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.