ArticleEnvironmental science & technology2021
Synthesis and Hydrolysis of Atmospherically Relevant Monoterpene-Derived Organic Nitrates.
Article in Environmental science & technology, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
5 citing papers in PubMed, 52 citations in OpenAlex.
- OH-Initiated Photooxidation of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates.Environmental science & technology · 2026Article
- Rapid Photolysis of Gaseous Organic Nitrates Formed from Hydroxyl and Nitrate Radical Oxidation of α‑Pinene and β‑Pinene.ACS ES&T air · 2025Article
- Multiphase reactions of organic peroxides and nitrite as a source of atmospheric organic nitrates.Nature communications · 2025Article
- Temperature-dependent composition of summertime PMACS earth & space chemistry · 2024Article
- Dissecting the contributions of organic nitrogen aerosols to global atmospheric nitrogen deposition and implications for ecosystems.National science review · 2023Article
Corrections and comments
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Authors and funding
6 authors at 2 institutions in 1 country.
Funding
Abstract
The partition of gas-phase organic nitrates (ONs) to aerosols and subsequent hydrolysis are regarded as important loss mechanisms for ON species. However, the hydrolysis mechanisms and the major factors controlling the hydrolysis lifetime are not fully understood. In this work, we synthesized seven monoterpene-derived ONs and systematically investigated their hydrolysis in bulk solutions at different pH values. The hydrolysis lifetimes ranged from 12.9 min to 8.5 h for allylic primary ON and tertiary ONs, but secondary ONs were stable at neutral pH. The alkyl substitution numbers, functional groups, and carbon skeletons were three important factors controlling hydrolysis rates. Tertiary and secondary ONs were found to hydrolyze via the acid-catalyzed unimolecular (S
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