ArticleChemical science2021
Selective crystallization
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed, 81 citations in OpenAlex.
- Ultrafast triggering of strong coupling in a semiconductor terahertz Fabry-Pérot cavity.Light, science & applications · 2026Article
- Emergence of Multiple Polaritonic States of Water-in-Salt in Cavity.Nanophotonics (Berlin, Germany) · 2026Article
- Cluster Formation and Phase Transitions Induced by Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2026Article
- Density-functional tight binding meets Maxwell: unraveling the mysteries of (strong) light-matter coupling efficiently.Nanophotonics (Berlin, Germany) · 2025Article
- The Diels-Alder Reaction as a Mechanistic Probe for Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2025Article
- Accessing a Hidden Pathway to Supramolecular Toroid through Vibrational Strong Coupling.Journal of the American Chemical Society · 2025Article
- Electronic strong coupling modifies the ground-state intermolecular interactions in self-assembled chlorin molecules.Nature communications · 2025Article
- Probing DNA melting behaviour under vibrational strong coupling.QRB discovery · 2025Article
- Measuring Kinetics under Vibrational Strong Coupling: Testing for a Change in the Nucleophilicity of Water and Alcohols.Angewandte Chemie (International ed. in English) · 2024Article
- Analytical Evaluation of Ground State Gradients in Quantum Electrodynamics Coupled Cluster Theory.Journal of chemical theory and computation · 2024Article
- Theory of Magnetic Properties in Quantum Electrodynamics Environments: Application to Molecular Aromaticity.Journal of chemical theory and computation · 2024Article
- Wide-Dynamic-Range Control of Quantum-Electrodynamic Electron Transfer Reactions in the Weak Coupling Regime.The journal of physical chemistry letters · 2024Article
- Consequences of Vibrational Strong Coupling on Supramolecular Polymerization of Porphyrins.Journal of the American Chemical Society · 2024Article
- Molecular Polaritons for Chemistry, Photonics and Quantum Technologies.Chemical reviews · 2024Review
- Collective Strong Coupling Modifies Aggregation and Solvation.The journal of physical chemistry letters · 2024Article
- Numerically Exact Solution for a Real Polaritonic System under Vibrational Strong Coupling in Thermodynamic Equilibrium: Loss of Light-Matter Entanglement and Enhanced Fluctuations.Journal of chemical theory and computation · 2023Article
- Unlimiting ionic conduction: manipulating hydration dynamics through vibrational strong coupling of water.Chemical science · 2023Article
- Theoretical Advances in Polariton Chemistry and Molecular Cavity Quantum Electrodynamics.Chemical reviews · 2023Review
- XRD and Spectroscopic Investigations of ZIF-Microchannel Glass Plates Composites.Materials (Basel, Switzerland) · 2023Article
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The coupling of (photo)chemical processes to optical cavity vacuum fields is an emerging method for modulating molecular and material properties. Recent reports have shown that strong coupling of the vibrational modes of solvents to cavity vacuum fields can influence the chemical reaction kinetics of dissolved solutes. This suggests that vibrational strong coupling might also effect other important solution-based processes, such as crystallization from solution. Here we test this hitherto unexplored notion, investigating pseudopolymorphism in the crystallization from water of ZIF metal-organic frameworks inside optical microcavities. We find that ZIF-8 crystals are selectively obtained from solution inside optical microcavities, where the OH stretching vibration of water is strongly coupled to cavity vacuum fields, whereas mixtures of ZIF-8 and ZIF-L are obtained otherwise. Moreover, ZIF crystallization is accelerated by solvent vibrational strong coupling. This work suggests that cavity vacuum fields might become a tool for materials synthesis, biasing molecular self-assembly and driving macroscopic material outcomes.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.