ArticleNature materials2022
Solvent-free autocatalytic supramolecular polymerization.
Article in Nature materials, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
14 citing papers in PubMed, 59 citations in OpenAlex.
- Supramolecular chemical ligation of helical polymers.Nature nanotechnology · 2026Article
- Solid-vapor synthesis of dynamic crystalline one-dimensional supramolecular polymers from amorphous macrocycles.Nature communications · 2026Article
- Beyond geometric constraint: dynamic fluid-lattice-activated topochemical polymerization.National science review · 2026Article
- Crystallization-driven template autocatalysis induces mirror symmetry breaking and amplification.Nature communications · 2026Article
- Unravelling the nucleation-elongation mechanism of one-pot catenation.Nature communications · 2026Article
- Crafting defects in two-dimensional organic platelets via seeded coassembly enables emergent molecular recognition.Nature communications · 2025Article
- Hydrogen-Bond-Directed Supramolecular Organic Semiconductor Thin Films Realized via Thermal Precursor Approach.Angewandte Chemie (International ed. in English) · 2025Article
- Noncovalent Synthesis of Topological Heterostructures Using a Site-Selective Electrostatic Co-Assembly Strategy.Angewandte Chemie (International ed. in English) · 2025Article
- Solvent-Free Supramolecular Polymerization for Feather-Like Nanostructured Chiral Fluorescent Polyurethanes with Multimodal Chiroptical Stimuli Responsiveness.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Chirality Evolution of Supramolecular Helices by Electron Transfer Assisted Secondary Nucleation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Water-regulated viscosity-plasticity phase transitions in a peptide self-assembled muscle-like hydrogel.Nature communications · 2025Article
- Differential perovskite hemispherical photodetector for intelligent imaging and location tracking.Nature communications · 2024Article
- A Bio-Based Supramolecular Adhesive: Ultra-High Adhesion Strengths at both Ambient and Cryogenic Temperatures and Excellent Multi-Reusability.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Article
- Spatiotemporal dynamics of supramolecular polymers byChemical science · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
10 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Solvent-free chemical manufacturing is one of the awaited technologies for addressing an emergent issue of environmental pollution. Here, we report solvent-free autocatalytic supramolecular polymerization (SF-ASP), which provides an inhibition-free template-assisted catalytic organic transformation that takes great advantage of the fact that the product (template) undergoes a termination-free nucleation-elongation assembly (living supramolecular polymerization) under solvent-free conditions. SF-ASP allows for reductive cyclotetramerization of hydrogen-bonding phthalonitriles into the corresponding phthalocyanines in exceptionally high yields (>80%). SF-ASP requires the growing polymer to form hexagonally packed crystalline fibres, which possibly preorganize the phthalonitriles at their cross-sectional edges for their efficient transformation. With metal oleates, SF-ASP produces single-crystalline fibres of metallophthalocyanines again in exceptionally high yields, which grow in both directions without terminal coupling until the phthalonitrile precursors are completely consumed. By taking advantage of this living nature of polymerization, multistep SF-ASP without/with metal oleates allows for the precision synthesis of multi-block supramolecular copolymers.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.