Evidence map›Paper›PMID 34636449›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021

Photochemical Hydrogen Evolution at Metal Centers Probed with Hydrated Aluminium Cations, Al

Jakob Heller, Tobias F Pascher, Christian van der Linde, Milan Ončák, Martin K Beyer

Open access · hybridAbstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
1.2field-weighted citation impact, top 21% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed, 9 citations in OpenAlex.

  1. The UV Photodissociation Spectrum of FeOHThe journal of physical chemistry. A · 2025
    Article
  2. Article
  3. Surface or Internal Hydration - Does It Really Matter?Journal of the American Society for Mass Spectrometry · 2023
    Review
  4. Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

Jakob HellerInstitut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25, 6020, Innsbruck, Austria.
Tobias F PascherInstitut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25, 6020, Innsbruck, Austria.ORCID http://orcid.org/0000-0002-8510-9114
Christian van der LindeInstitut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25, 6020, Innsbruck, Austria.ORCID http://orcid.org/0000-0003-0493-820X
Milan OnčákInstitut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25, 6020, Innsbruck, Austria.ORCID http://orcid.org/0000-0002-4801-3068
Martin K BeyerInstitut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25, 6020, Innsbruck, Austria.ORCID http://orcid.org/0000-0001-9373-9266
Universität Innsbruck · AT

Funding

Austrian Federal Ministry of Education, Science and Research Innsbruck Laser Core FacilityAustrian Science Fund M2001Austrian Science Fund P29174Austrian Science Fund W1259-N27Austrian Science Fund FWF P 29174Austrian Science Fund FWF W 1259Universität Innsbruck HPC Infrastructure LEO
6 · The paper itself

Abstract

Hydrated aluminium cations have been investigated as a photochemical model system with up to ten water molecules by UV action spectroscopy in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Intense photodissociation was observed starting at 4.5 eV for two to eight water molecules with loss of atomic hydrogen, molecular hydrogen and water molecules. Quantum chemical calculations for n=2 reveal that solvation shifts the intense 3s-3p excitations of Al

Indexed as

conical intersectionshydrationmultireference calculationswater clusterswater splitting

Identifiers

PMID34636449
PMCPMC9298212
OpenAlexW3207275313

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.