ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Cobalt-Catalyzed Dehydrogenative C-H Silylation of Alkynylsilanes.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
9 citing papers in PubMed.
- Cobalt-Catalyzed Intramolecular C─H Silylation of Arenes.Angewandte Chemie (International ed. in English) · 2026Article
- Triazine-based cobalt pincer complex for regioselective C-H borylation of furans.Scientific reports · 2026Article
- Structurally Constrained Cyclic (Diacyloxyiodo)Arenes as an Enabling Platform for Hypervalent Iodine(III) Chemistry.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Cobalt-Catalyzed Reduction of Aldehydes to Alcohols via the Hydroboration Reaction.International journal of molecular sciences · 2024Article
- Carboxylate-CatalyzedOrganic letters · 2024Article
- Diazines and Triazines as Building Blocks in Ligands for Metal-Mediated Catalytic Transformations.ACS organic & inorganic Au · 2024Review
- Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes.Organic letters · 2023Article
- Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species.Scientific reports · 2023Article
- Cobalt-Catalyzed Dehydrogenative C-H Silylation of Alkynylsilanes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Herein, we report that a cobalt catalyst permits the general synthesis of substituted alkynylsilanes through dehydrogenative coupling of alkynylsilanes and hydrosilanes. Several silylated alkynes, including di- and trisubstituted ones, were prepared in a one-step procedure. Thirty-seven compounds were synthesized for the first time by applying our catalyst system. The alkynylsilanes bearing hydrosilyl moieties provide an opportunity for further functionalization (e. g., hydrosilylation). The use of primary silanes as substrates and precatalyst activators permits the use of inexpensive and easily accessible 3d metal precatalysts, and avoids the presence of additional activators.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.