ArticleNature communications2021
Regio- and sequence-controlled conjugated topological oligomers and polymers via boronate-tag assisted solution-phase strategy.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 50 citations in OpenAlex.
- Sequence-defined donor-acceptor-donor oligo(para-phenylene ethynylene)s with emission across the visible spectrum.Scientific reports · 2026Article
- Enhanced B-N coordinated dynamic boronate chemistry for recyclable thermosets with elevated stability.Nature communications · 2026Article
- Topology-controlled dynamic conjugated oligomers from tetra-arylsubstituted alkene building blocks.Nature communications · 2026Article
- Regioregular Alternating Polychalcogenophenes-Block-Poly(3-hexylthiophene): Synthesis, Structural Characterizations, Molecular Properties, and Transistors.Chemistry, an Asian journal · 2025Article
- High-Throughput Synthesis, Purification, and Application of Alkyne-Functionalized Discrete Oligomers.Journal of the American Chemical Society · 2024Article
- Installing a Single Monomer within Acrylic Polymers Using Photoredox Catalysis.Journal of the American Chemical Society · 2024Article
- Oligomers from the Synthetic Polymers: Another Potential Iceberg of New Pollutants.Environment & health (Washington, D.C.) · 2023Review
- Backbone Engineering of Monodisperse Conjugated Polymers via Integrated Iterative Binomial Synthesis.Journal of the American Chemical Society · 2023Article
- Sequence-controlled alternating block polychalcogenophenes: synthesis, structural characterization, molecular properties, and transistors for bromine detection.Chemical science · 2023Article
- Design of Microstructure-Engineered Polymers for Energy and Environmental Conservation.JACS Au · 2023Review
Corrections and comments
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Authors and funding
7 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The regulation of polymer topology and the precise control over the monomer sequence is crucial and challenging in polymer science. Herein, we report an efficient solution-phase synthetic strategy to prepare regio- and sequence-controlled conjugated polymers with topological variations via the usage of methyliminodiacetic acid (MIDA) boronates. Based on the solubility of MIDA boronates and their unusual binary affinity for silica gel, the synthesized regio- and sequence-defined conjugated oligomers can be rapidly purified via precipitation or automatic liquid chromatography. These synthesized discrete oligomers can be used for iterative exponential and sequential growth to obtain linear and dendrimer-like star polymers. Moreover, different topological sequence-controlled conjugated polymers are conveniently prepared from these discrete oligomers via condensation polymerization. By investigating the structure-property relationship of these polymers, we find that the optical properties are strongly influenced by the regiochemistry, which may give inspiration to the design of optoelectronic polymeric materials.
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Registered trials
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