ReviewChemical reviews2022
Chiral Photocatalyst Structures in Asymmetric Photochemical Synthesis.
Review in Chemical reviews, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 100 papers.
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Who cites it
100 citing papers in PubMed.
- Shaping light in 3D for direct asymmetric photochemistry: a 1000-fold enantioselectivity enhancement.Nature communications · 2026Article
- Excitation of acyclic trisubstituted alkenes via triplet energy transfer for diastereo- and enantioselective [2 + 2] photocycloaddition.Nature communications · 2026Article
- Persistent Halogenated Perylenediimide Organic Radical Anions Orchestrating Three-Photon Energy Conversion and Programmable Molecular Coupling.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Chemo-, Diastereo-, and Enantioselective Radical Cyclization of Enals to Access Cyclopentanols Bearing an α-Quaternary Center.Angewandte Chemie (International ed. in English) · 2026Article
- Tuning the Disordered Structure: Recent Advances in Amorphization Engineering for Enhanced Photocatalysis.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Article
- Unraveling the mechanistic origins of efficiency and stereoselectivity in EDA-mediated photocatalysis.Nature communications · 2026Article
- Photochemical Deracemization of Aza-1-isoindolinones: Critical Influence of Catalyst Substitution and the Nature of Its Resting State.Journal of the American Chemical Society · 2026Article
- Bifunctional Photocatalysts: Exploiting Proximity for Enhanced Reaction Performance.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Review
- Photofracking-Assisted Enhancement of Solid-State Photochemical Reactivity: α-Azido-5-phenyl-2,4-dienoate Derivatives.Journal of the American Chemical Society · 2026Article
- Chiral Brønsted acid-catalyzed kinetic resolution of radical additions.Nature communications · 2026Article
- Catalytic Scalable Synthesis of Polyketides Enabled by Chiral Brønsted Acid-Catalyzed Asymmetric Allylborations.Chemical record (New York, N.Y.) · 2026Review
- Cooperative NHC and Photoredox Dual Catalysis for the Construction of Carbonyl Compounds.ACS omega · 2026Review
- Sustainable and Scalable Flow Photochemical Conversions Using a Labile Ligand-Assembled Iron Complex.JACS Au · 2026Article
- Photochemical Deracemization of Chromanes and its Application to the Synthesis of Enantiopure Bioactive Compounds.Angewandte Chemie (International ed. in English) · 2026Article
- Fused 3D boron heterocyclesChemical science · 2026Article
- Triplet state reactivity of iminium ions in organocatalytic asymmetric [2 + 2] photocycloadditions.Nature chemistry · 2026Article
- Boron-Enabled Stereoselective Synthesis of Polysubstituted Housanes.Journal of the American Chemical Society · 2025Article
- Catalytic Enantioselective [6π] Photocyclization Reactions by Chromophore Activation with a Chiral Lewis Acid.Journal of the American Chemical Society · 2025Article
- Construction of sulfur stereocentres by asymmetric geminate recasting.Nature chemistry · 2025Article
40 more citing papers are in PubMed but not listed here.
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Asymmetric catalysis is a major theme of research in contemporary synthetic organic chemistry. The discovery of general strategies for highly enantioselective photochemical reactions, however, has been a relatively recent development, and the variety of photoreactions that can be conducted in a stereocontrolled manner is consequently somewhat limited. Asymmetric photocatalysis is complicated by the short lifetimes and high reactivities characteristic of photogenerated reactive intermediates; the design of catalyst architectures that can provide effective enantiodifferentiating environments for these intermediates while minimizing the participation of uncontrolled racemic background processes has proven to be a key challenge for progress in this field. This review provides a summary of the chiral catalyst structures that have been studied for solution-phase asymmetric photochemistry, including chiral organic sensitizers, inorganic chromophores, and soluble macromolecules. While some of these photocatalysts are derived from privileged catalyst structures that are effective for both ground-state and photochemical transformations, others are structural designs unique to photocatalysis and offer insight into the logic required for highly effective stereocontrolled photocatalysis.
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