ArticleAngewandte Chemie (International ed. in English)2021
Tris(pentafluorophenyl)borane-Catalyzed Carbenium Ion Generation and Autocatalytic Pyrazole Synthesis-A Computational and Experimental Study.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Atom-economic and stereoselective catalytic synthesis of fully substituted enol esters/carbonates of amides in acyclic systems enabled by boron Lewis acid catalysis.Chemical science · 2023Article
- Reactions of Diethylazo-Dicarboxylate with Frustrated Lewis Pairs.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Reactions of Frustrated Lewis Pairs with Chloro-Diazirines: Cleavage of N=N Double Bonds.Angewandte Chemie (International ed. in English) · 2022Article
- Lewis Acid Assisted Brønsted Acid Catalysed Decarbonylation of Isocyanates: A Combined DFT and Experimental Study.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Understanding the Influence of Donor-Acceptor Diazo Compounds on the Catalyst Efficiency of B(CChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Tris(pentafluorophenyl)borane-Catalyzed Carbenium Ion Generation and Autocatalytic Pyrazole Synthesis-A Computational and Experimental Study.Angewandte Chemie (International ed. in English) · 2021Article
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Authors and funding
8 authors.
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Abstract
In recent years, metal-free organic synthesis using triarylboranes as catalysts has become a prevalent research area. Herein we report a comprehensive computational and experimental study for the highly selective synthesis of N-substituted pyrazoles through the generation of carbenium species from the reaction between aryl esters and vinyl diazoacetates in the presence of catalytic tris(pentafluorophenyl)borane [B(C
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