Evidence map›Paper›PMID 34588921›Full record

ArticleEuropean journal of inorganic chemistry2021

Rhodocenium Functionalization Enabled by Half-Sandwich Capping, Zincke Reaction, Diazoniation and Sandmeyer Chemistry.

Markus Wiedemair, Holger Kopacka, Klaus Wurst, Thomas Müller, Klaus Eichele, Stefan Vanicek, Stephan Hohloch, Benno Bildstein

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In one paragraph

Article in European journal of inorganic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Coexistence of Metallocene Cations and Anions.Journal of the American Chemical Society · 2025
    Article
  2. Magnetic resonance (Gottingen, Germany) · 2024
    Article
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Markus WiedemairInstitute of General, Inorganic and Theoretical Chemistry University of Innsbruck Center for Chemistry and Biomedicine Innrain 80-82 6020 Innsbruck Austria.
Holger KopackaInstitute of General, Inorganic and Theoretical Chemistry University of Innsbruck Center for Chemistry and Biomedicine Innrain 80-82 6020 Innsbruck Austria.
Klaus WurstInstitute of General, Inorganic and Theoretical Chemistry University of Innsbruck Center for Chemistry and Biomedicine Innrain 80-82 6020 Innsbruck Austria.
Thomas MüllerInstitute of Organic Chemistry University of Innsbruck, Center for Chemistry and Biomedicine, Innrain 80-82 6020 Innsbruck Austria.
Klaus EicheleInstitut für Anorganische Chemie Universität Tübingen Auf der Morgenstelle 18 72076 Tübingen Germany.
Stefan VanicekInstitute of General, Inorganic and Theoretical Chemistry University of Innsbruck Center for Chemistry and Biomedicine Innrain 80-82 6020 Innsbruck Austria.
Stephan HohlochInstitute of General, Inorganic and Theoretical Chemistry University of Innsbruck Center for Chemistry and Biomedicine Innrain 80-82 6020 Innsbruck Austria.
Benno BildsteinInstitute of General, Inorganic and Theoretical Chemistry University of Innsbruck Center for Chemistry and Biomedicine Innrain 80-82 6020 Innsbruck Austria.ORCID 0000-0003-1969-1334

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

In continuation of our exploration of metallocenium chemistry we report here on innovative ways toward monofunctionalized rhodocenium salts applying half-sandwich capping reactions of cyclopentadienyl rhodium(III) halide synthons with cyclopentadienyl ylides containing pyridine, phosphine or dinitrogen leaving groups, followed by Zincke and Sandmeyer reactions. Thereby amino, diazonio, bromo, azido and iodo rhodocenium salts containing valuable functional groups are accessible for the first time. Target compounds were characterized by spectroscopic (

Indexed as

MetallocenesMolecular electrochemistryRhodiumSandwich complexesStructure elucidation

Identifiers

PMID34588921
PMCPMC8456843

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.