Evidence map›Paper›PMID 34588466›Full record

ArticleScientific reports2021

Fluorescence quenching based detection of nitroaromatics using luminescent triphenylamine carboxylic acids.

Aamnayee Mishra, R Dheepika, P A Parvathy, P M Imran, N S P Bhuvanesh, S Nagarajan

Open access · goldAbstract read
In one paragraph

Article in Scientific reports, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
2.9field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed, 49 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 3 institutions in 2 countries.

Aamnayee MishraDepartment of Chemistry, Central University of Tamil Nadu, Thiruvarur, 610 005, India.
R DheepikaDepartment of Chemistry, Central University of Tamil Nadu, Thiruvarur, 610 005, India.
P A ParvathyDepartment of Chemistry, Central University of Tamil Nadu, Thiruvarur, 610 005, India.
P M ImranDepartment of Chemistry, Islamiah College, Vaniyambadi, 635 752, India.
N S P BhuvaneshDepartment of Chemistry, Texas A&M University, College Station, TX, 77842, USA.
S NagarajanDepartment of Chemistry, Central University of Tamil Nadu, Thiruvarur, 610 005, India. snagarajan@cutn.ac.in.
Central University of Tamil Nadu · INM.S. Ramaiah Medical College · INTexas A&M University · US

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Detection of nitroaromatics employing greener techniques has been one of the most active research fields in chemistry. A series of triphenylamine (TPA) functionalized carboxylic acids were synthesized and characterized using various spectroscopic techniques including single-crystal X-ray diffraction analysis. The interaction of carboxylic acid-decorated TPAs with nitroaromatic compounds was photophysically explored using absorption and emission spectroscopy. Stern-Volmer plot accounts for the appreciable quenching constant of the TPA-acids. Density functional theory calculations were carried out to study the new compounds' frontier molecular orbital energy levels and the possible interactions with picrate anion and revealed an unusual charge transfer interaction between acids and picrate anion. The contact mode detection shows the TPA-acids can be used as dip-strip sensors for picric acid detection.

Identifiers

PMID34588466
PMCPMC8481287
OpenAlexW3204866700

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.