Evidence map›Paper›PMID 34586823›Full record

ArticleThe Journal of organic chemistry2021

Biphenyl Cyclobutenone Photoelectrocyclizations.

Changhang Dai, Xuchen Zhao, Changqing Song, Zach Schwartz, Jon D Rainier

Abstract read
In one paragraph

Article in The Journal of organic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Changhang DaiDepartment of Chemistry, University of Utah, 315 South, 1400 East, Salt Lake City, Utah 84112, United States.
Xuchen ZhaoDepartment of Chemistry, University of Utah, 315 South, 1400 East, Salt Lake City, Utah 84112, United States.
Changqing SongDepartment of Chemistry, University of Utah, 315 South, 1400 East, Salt Lake City, Utah 84112, United States.
Zach SchwartzDepartment of Chemistry, University of Utah, 315 South, 1400 East, Salt Lake City, Utah 84112, United States.
Jon D RainierDepartment of Chemistry, University of Utah, 315 South, 1400 East, Salt Lake City, Utah 84112, United States.ORCID 0000-0003-4386-2463

Funding

Supplemental Funding Request for Photochemical Electrocyclizations to Virulence Inhibiting Natural Products]R01GM132531 · NIGMS · UNIVERSITY OF UTAH · PI RAINIER, JON DOUGLAS · 2019 to 2022
$1.3M
NIGMS NIH HHS R01 GM132531
6 · The paper itself

Abstract

In this work, we demonstrate that readily available conjugated bis-aryl cyclobutenones undergo photoelectrocyclization reactions to give the corresponding dihydrophenanthrene cyclobutanones when exposed to 350 nm light, TFA, and TMSCl. We have also found that cyclobutenone electrocyclizations and cycloreversions are in equilibrium.

Indexed as

CyclobutanesBiphenyl CompoundsbiphenylBiphenyl CompoundsCyclobutanescyclobutenone

Identifiers

PMID34586823
PMCPMC8794574

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.