ArticleAngewandte Chemie (International ed. in English)2021
Copper Pairing in the Mordenite Framework as a Function of the Cu
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Thermochemical-dependent Cu(i) siting and mobility in Cu-CHA revealed by XAS and quantum mechanical simulations.Chemical science · 2026Article
- In situ synthesis of copper-based mordenite for nitrogen/methane sieving.Nature communications · 2025Article
- Biomimetic single Al-OH site with high acetylcholinesterase-like activity and self-defense ability for neuroprotection.Nature communications · 2023Article
- Understanding C-H activation in light alkanes over Cu-MOR zeolites by coupling advanced spectroscopy and temperature-programmed reduction experiments.Chemical science · 2023Article
- Methane Oxidation to Methanol.Chemical reviews · 2023Review
- Influence of ion mobility on the redox and catalytic properties of Cu ions in zeolites.Chemical science · 2022Review
- Assessing the Influence of Zeolite Composition on Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-CHA DeNOThe journal of physical chemistry letters · 2022Article
- Titration of Cu(I) Sites in Cu-ZSM-5 by Volumetric CO Adsorption.ACS applied materials & interfaces · 2022Article
- Copper Pairing in the Mordenite Framework as a Function of the CuAngewandte Chemie (International ed. in English) · 2021Article
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Authors and funding
7 authors.
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Abstract
A series of gas-phase reactants is used to treat a Cu-exchanged mordenite zeolite with the aim of studying the influence of the reaction environment on the formation of Cu pairs. The rearrangement of Cu ions to form multimeric sites as a function of their oxidation state was probed by X-ray absorption spectroscopy (XAS) and also by applying advanced analysis through wavelet transform, a method able to specifically locate Cu-Cu interactions also in the presence of overlapping contributions from other scattering paths. The nature of the Cu-oxo species formed upon oxidation was further crosschecked by DFT-assisted fitting of the EXAFS data and by resonant Raman spectroscopy. Altogether, the Cu
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