ArticleChemical communications (Cambridge, England)2021
Exploring the stability of the NHC-metal bond using thiones as probes.
Article in Chemical communications (Cambridge, England), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Carbene-tellurium adducts as colorimetric probes for the stereo-electronic profiles of carbenes in solution, and as carbene-transfer agents.Chemical science · 2026Article
- Metals in Cancer Research: Beyond Platinum Metallodrugs.ACS central science · 2024Review
- Advances in Emerging Catalytic Materials for the Conversion of Carbon Dioxide.Materials (Basel, Switzerland) · 2023Review
- Electronic Effects of Support Doping on Hydrotalcite-Supported Iridium N-Heterocyclic Carbene Complexes.ACS omega · 2022Article
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The metal-carbon bond in N-heterocyclic carbene (NHC) metal complexes, which are ubiquitous in modern homogeneous catalysis, is often conjectured to be robust. Here, carbene dissociation was evaluated from a series of complexes with metals of relevance in catalysis containing either an Arduengo-type 2-imidazolylidene or a mesoionic 1,2,3-triazolylidene ligand through thione formation, revealing remarkable kinetic lability of the NHC-metal bond for,
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