ArticleACS omega2021
Experimental Measurement and Equilibrium Modeling of Adsorption of Asphaltenes from Various Origins onto the Magnetite Surface under Static and Dynamic Conditions.
Article in ACS omega, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Application of Robust Neural Networks to Modeling Crude Oil Viscosity Reduction Using Nanoparticles.ACS omega · 2025Article
- An experimental study of the effects of bacteria on asphaltene adsorption and wettability alteration of dolomite and quartz.Scientific reports · 2023Article
- Experimental measurement and modeling of asphaltene adsorption onto iron oxide and lime nanoparticles in the presence and absence of water.Scientific reports · 2023Article
- Effect of Magnetized Coagulants on Wastewater Treatment: Rice Starch and Chitosan Ratios Evaluation.Polymers · 2022Article
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Wettability alterations, permeability reduction of reservoir rocks, and oil production decline may occur as a consequence of asphaltene adsorption and deposition on the surfaces of oil reservoir rocks. Magnetite and other iron minerals are abundant in the rock composition of sandstone reservoirs and cause problems by precipitation and adsorption of polar components of crude oil. The main purpose of this study was to investigate the adsorption of six asphaltene samples of various origins onto the magnetite surface. Characterization of magnetite was performed by Brunauer-Emmett-Teller (BET), Fourier transform infrared spectroscopy (FTIR), and X-ray fluorescence (XRF). Also, FTIR, dynamic light scattering (DLS), and elemental analysis were performed to characterize asphaltenes. Static and dynamic adsorption experiments were carried out to investigate the effects of the water phase, adsorbent size, flow rate, and asphaltene compositions on asphaltene uptake by the magnetite. The results showed that an increase in the nitrogen content and aromatic nature of asphaltenes increased their adsorption on magnetite. The addition of water to the adsorption tests significantly reduced the adsorption amount of asphaltenes on the magnetite. A considerable decrease in asphaltene adsorption was observed with an increase in the flow rate in dynamic tests. This shows that higher flow rates reduce the interaction between adsorbed asphaltenes and asphaltene aggregates in the solution, which reduces the uptake of more asphaltenes. Moreover, adsorbed asphaltene components with a weaker bond are detached from the magnetite surface, which can be attributed to the physisorption of asphaltenes. Eventually, four well-known adsorption isotherm models, namely, Langmuir, Dubinin-Radushkevich, Temkin, and Freundlich were utilized to find the mechanisms of asphaltene adsorption onto the magnetite surface. The Freundlich model seems to provide better estimates for the adsorption of asphaltenes on the magnetite surface. The findings of this study render insights into the better management of oil production in formations with iron-containing rocks.
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