ReviewAccounts of chemical research2021
Dinickel Active Sites Supported by Redox-Active Ligands.
Review in Accounts of chemical research, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
17 citing papers in PubMed, 57 citations in OpenAlex.
- Defined Dinuclear Nickel Sites on Mesoporous Silica Translate Molecular Surface Mimics to Heterogeneous Catalysis.Angewandte Chemie (International ed. in English) · 2026Article
- Long-range metal-metal cooperative nitrile activation in 1,8-diazaanthracene-supported dicopper complexes.Chemical communications (Cambridge, England) · 2026Article
- Deoxygenative Single-Carbon Atom Transfer: Accessing Strained Carbocycles From Alkenes and Aldehydes With Designer Dual-Functional Reagent.Angewandte Chemie (International ed. in English) · 2026Article
- Breaking the blue limit of non-conjugated hydrocarbons via multiple through-space interactions.National science review · 2026Article
- Clean energy storage devices in electricity market under dual carbon goals: assembly and performance of supercapacitors.Scientific reports · 2026Article
- Catalytic Enantioselective Cross-Nucleophile Coupling via Valence Tautomerism.Journal of the American Chemical Society · 2025Article
- Air-Stable Cobalt-Semiquinone Radical Complexes on Carbon Nanotubes: A Redox Switch for Anion Response.Journal of the American Chemical Society · 2025Article
- Alkyne Dihydroboration viaJournal of the American Chemical Society · 2025Article
- Dinickel-catalyzed enantioselective reductive addition of imines with vinyl halides.Nature communications · 2025Article
- Artificial Chiral Trinuclear Zn Catalysts: Design, Self-Assembly and Unprecedented Efficiency in Asymmetric Hydroboration of Ketones.ACS central science · 2025Article
- Synthesis and Characterization of Bimetallic Copper(I) Complexes Supported by a Hexadentate Naphthyridine-Based Macrocycle Ligand.Inorganic chemistry · 2025Article
- Access to Heterobimetallic MInorganic chemistry · 2025Article
- Article
- Reactivity Profile of a Formally Dicobalt(0) Complex Bound by a Redox-Active Macrocycle.Organometallics · 2024Article
- Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranesChemical science · 2024Article
- Binuclear Complexes Supported by a Tetrapyridyl Ligand with a Bending Anthraquinodimethane Linker.ACS organic & inorganic Au · 2023Article
- Heteroligand Metal Complexes with Extended Redox Properties Based on Redox-Active Chelating Ligands of o-Quinone Type and Ferrocene.Molecules (Basel, Switzerland) · 2022Review
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
Redox reactions that take place in enzymes and on the surfaces of heterogeneous catalysts often require active sites that contain multiple metals. By contrast, there are very few homogeneous catalysts with multinuclear active sites, and the field of organometallic chemistry continues to be dominated by the study of single metal systems. Multinuclear catalysts have the potential to display unique properties owing to their ability to cooperatively engage substrates. Furthermore, direct metal-to-metal covalent bonding can give rise to new electronic configurations that dramatically impact substrate binding and reactivity. In order to effectively capitalize on these features, it is necessary to consider strategies to avoid the dissociation of fragile metal-metal bonds in the course of a catalytic cycle. This Account describes one approach to accomplishing this goal using binucleating redox-active ligands.In 2006, Chirik showed that pyridine-diimines (PDI) have sufficiently low-lying π* levels that they can be redox-noninnocent in low-valent iron complexes. Extending this concept, we investigated a series of dinickel complexes supported by naphthyridine-diimine (NDI) ligands. These complexes can promote a broad range of two-electron redox processes in which the NDI ligand manages electron equivalents while the metals remain in a Ni(I)-Ni(I) state.Using (NDI)Ni
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.