Odor-Based Nanomechanical Discrimination of Fuel Oils Using a Single Type of Designed Nanoparticles with Nonlinear Viscoelasticity.

Odors are one of the most diverse and complicated gaseous mixtures so that their discrimination is challenging yet attractive because of the rich information about their origin. The more similar the properties of odors are, the more difficult the discrimination becomes. The practical applications, however, often demand such discrimination, especially with a compact sensing platform. In this paper, we show that a nanomaterial designed for a specific type of odors can clearly discriminate them even with a single nanomechanical sensing channel. Fuel oils and their mixture are used as a model target that has similar chemical properties but different compositions mainly consisting of paraffinic, olefinic, naphthenic, and aromatic hydrocarbons. We demonstrate using octadecyl functionalized silica-titania nanoparticles that the difference in the compositions is successfully picked up based on their high affinity for the aliphatic hydrocarbons and alkyl chain length dependent nonlinear viscoelastic behavior. Such a properly designed material is proved to derive sufficient information from a series of analytes to discriminate them even with a single sensing element. This approach provides a guideline to prepare various sensors whose response properties are distinct and optimized depending on applications.