Evidence map›Paper›PMID 34546749›Full record

ArticleJournal of the American Chemical Society2021

High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C-H Thianthrenation.

Fabio Juliá, Qianzhen Shao, Meng Duan, Matthew B Plutschack, Florian Berger, Javier Mateos, Chenxi Lu, Xiao-Song Xue, K N Houk, Tobias Ritter

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 30 papers.

0numbers the graph read from it
0cells of the map it votes in
30citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

30 citing papers in PubMed.

  1. Review
  2. Review
  3. Article
  4. Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross-Coupling.Angewandte Chemie (International ed. in English) · 2026
    Article
  5. Thianthrenium Salts in Photochemistry.Accounts of chemical research · 2026
    Article
  6. Investigation of olefins as a cocatalyst for halonium catalysis.Chemical communications (Cambridge, England) · 2026
    Article
  7. Article
  8. Article
  9. Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Article
  15. Meta-Dimethylation of Arenes via Catellani Reaction from Aryl Thianthrenium Salts.Angewandte Chemie (International ed. in English) · 2025
    Article
  16. Article
  17. Article
  18. Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Fabio JuliáMax-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm Platz 1, D-45470 Mülheim an der Ruhr, Germany.ORCID 0000-0001-8903-4482
Qianzhen ShaoDepartment of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569 United States.
Meng DuanDepartment of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569 United States.
Matthew B PlutschackMax-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm Platz 1, D-45470 Mülheim an der Ruhr, Germany.
Florian BergerMax-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm Platz 1, D-45470 Mülheim an der Ruhr, Germany.
Javier MateosMax-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm Platz 1, D-45470 Mülheim an der Ruhr, Germany.ORCID 0000-0002-2358-9183
Chenxi LuDepartment of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569 United States.
Xiao-Song XueDepartment of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569 United States.ORCID 0000-0003-4541-8702
K N HoukDepartment of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569 United States.ORCID 0000-0002-8387-5261
Tobias RitterMax-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm Platz 1, D-45470 Mülheim an der Ruhr, Germany.ORCID 0000-0002-6957-450X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The introduction of thianthrene as a linchpin has proven to be a versatile strategy for the C-H functionalization of aromatic compounds, featuring a broad scope and fast diversification. The synthesis of aryl thianthrenium salts has displayed an unusually high

Identifiers

PMID34546749
PMCPMC8499029

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.