ArticleiScience2021
Electrospun rhodamine@MOF/polymer luminescent fibers with a quantum yield of over 90.
Article in iScience, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed, 23 citations in OpenAlex.
- A Development and Comparison Study of PVDF Membranes Enriched by Metal-Organic Frameworks.Polymers · 2025Article
- Triboelectric Nanogenerators Based on Composites of Zeolitic Imidazolate Frameworks Functionalized with Halogenated Ligands for Contact and Rotational Mechanical Energy Harvesting.ACS applied nano materials · 2025Article
- Stimuli-Responsive Electrospun Fluorescent Fibers Augmented with Aggregation-Induced Emission (AIE) for Smart Applications.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
- Turn-On Fluorescence Chemical Sensing through Transformation of Self-Trapped Exciton States at Room Temperature.ACS sensors · 2022Article
- Confinement of Luminescent Guests in Metal-Organic Frameworks: Understanding Pathways from Synthesis and Multimodal Characterization to Potential Applications of LG@MOF Systems.Chemical reviews · 2022Review
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Tailored luminescent guest@metal-organic framework (Guest@MOF) materials with outstanding photophysical properties are enabling materials for emergent technologies in smart sensors and optoelectronics. However, the practical utility of Guest@MOF currently is impaired by its poor stability and difficult-to-handle powder form. Here, we combine a luminescent-sensing Guest@MOF system with a non-luminescent polymer matrix and, for the first time, demonstrated the easy-to-apply electrospinning of luminescent fibers comprising nanocrystals of RhB@ZIF-71 (rhodamine B@zeolitic imidazolate framework-71) homogeneously dispersed in a polyvinylidene difluoride (PVDF) matrix. The luminescence of RhB@ZIF-71/PVDF fiber is tunable and exhibits a quantum yield exceeding 90%. Compared with RhB fluorophore in PVDF fiber, the ZIF-71 (host) protects the nanoconfined RhB guest molecules (especially the J-aggregates of RhB), giving the composite fiber its unique thermofluorochromic response and enhanced thermal stability to 200°C. Our results reveal the exciting opportunities for implementing electrospun luminescent fibers functionalized with bespoke Guest@MOF nanocrystals for multifunctional device applications.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.