Evidence map›Paper›PMID 34522298›Full record

ArticleChemical science2021

Lewis acid catalyzed heavy atom tunneling - the case of 1

Stefan Henkel, Melania Prado Merini, Enrique Mendez-Vega, Wolfram Sander

Abstract read
In one paragraph

Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Simultaneous Tunneling Control in Conformer-Specific Reactions.Journal of the American Chemical Society · 2022
    Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Stefan HenkelLehrstuhl für Organische Chemie II, Ruhr-Universität Bochum 44801 Bochum Germany wolfram.sander@rub.de.ORCID https://orcid.org/0000-0003-3362-8825
Melania Prado MeriniLehrstuhl für Organische Chemie II, Ruhr-Universität Bochum 44801 Bochum Germany wolfram.sander@rub.de.ORCID https://orcid.org/0000-0002-9923-2156
Enrique Mendez-VegaLehrstuhl für Organische Chemie II, Ruhr-Universität Bochum 44801 Bochum Germany wolfram.sander@rub.de.ORCID https://orcid.org/0000-0001-5833-8520
Wolfram SanderLehrstuhl für Organische Chemie II, Ruhr-Universität Bochum 44801 Bochum Germany wolfram.sander@rub.de.ORCID https://orcid.org/0000-0002-1640-7505

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

For many thermal reactions, the effects of catalysis or the influence of solvents on reaction rates can be rationalized by simple transition state models. This is not the case for reactions controlled by quantum tunneling, which do not proceed

Identifiers

PMID34522298
PMCPMC8386641

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.