ArticleNature communications2021
Tunable and functional deep eutectic solvents for lignocellulose valorization.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 48 papers.
What it found
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The trial behind it
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Who cites it
48 citing papers in PubMed.
- Lignin separation modification and high-value utilization based on low eutectic solvents: a review.Bioresources and bioprocessing · 2026Review
- Regenerated lignocellulosic material from pea, bean, and artichoke waste as feedstock for bioplastic production.Journal of advanced research · 2026Article
- Overcoming Biomass Recalcitrance Heterogeneity Using a Surfactant-Based CTAB/LA/CuApplied biochemistry and biotechnology · 2026Article
- Lignin-dynamic networks break the strength-toughness trade-off in thermoplastic elastomers.Nature communications · 2026Article
- Preacetylation of Kraft Lignin Facilitates Acid-Catalyzed Depolymerization in Acidic Deep Eutectic Solvents to Obtain Lignin Oil With High Antioxidant Activity.ChemSusChem · 2026Article
- A Study on the Effects of Deep Eutectic Solvent (Chcl-Eg) Pretreatment on the Mechanical and Dimensional Stability Properties of Densified Chinese Fir.Materials (Basel, Switzerland) · 2026Article
- The One-Step Synthesis of Biologically Active Isochromans from Lignin-Derived Aromatic Monomers in Tunable Deep Eutectic Solvents.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- An Eco-Efficient and Sustainable Strategy for Fabricating High-Strength Agricultural Fibers.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Sequential Pyruvic Acid Pretreatment and Alkaline Extraction of Bamboo Leaf Phenolics: Two-Stage Mass Transfer Kinetics.Foods (Basel, Switzerland) · 2026Article
- Article
- Navigating the Forest of Lignin-Derived Monomers for Polymer Synthesis.Biomacromolecules · 2026Review
- A Fully Bio-Based Elastomer with Ultrahigh Lignin Content and Performance Rivaling Nitrile Rubber.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Review
- Third-Component-Regulated Choline Chloride-Monoethanolamine-Based Solvent Systems for Enhanced Valorization of Bamboo Toward Concurrent Bioethanol and Carbon Dot Production.Molecules (Basel, Switzerland) · 2026Article
- Rye Straw Lignin as a Promising Source of Tricin: Varietal Differences and Its Release Using Deep Eutectic Solvents.ACS sustainable chemistry & engineering · 2026Article
- Enhancing the Value Added of Lignin Extracted fromPolymers · 2026Article
- Alcohol-Decorated Lignins for Nanoparticle Formation through Reactive Fractionation in Ternary Deep Eutectic Solvent Systems.ACS sustainable chemistry & engineering · 2026Article
- Condensed lignin depolymerization via C-C bond cleavage with a disordered crystalline mesoporous zeolite.Nature communications · 2026Article
- Aqueously Upcycled Lignin with Emergent Tribonegativity for Skin-Integrated Triboelectronics.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Exploring Lignin Conformation in Organic and Deep Eutectic Solvents Using Small-Angle Neutron Scattering.Langmuir : the ACS journal of surfaces and colloids · 2026Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Stabilization of reactive intermediates is an enabling concept in biomass fractionation and depolymerization. Deep eutectic solvents (DES) are intriguing green reaction media for biomass processing; however undesired lignin condensation is a typical drawback for most acid-based DES fractionation processes. Here we describe ternary DES systems composed of choline chloride and oxalic acid, additionally incorporating ethylene glycol (or other diols) that provide the desired 'stabilization' function for efficient lignocellulose fractionation, preserving the quality of all lignocellulose constituents. The obtained ethylene-glycol protected lignin displays high β-O-4 content (up to 53 per 100 aromatic units) and can be readily depolymerized to distinct monophenolic products. The cellulose residues, free from condensed lignin particles, deliver up to 95.9 ± 2.12% glucose yield upon enzymatic digestion. The DES can be recovered with high yield and purity and re-used with good efficiency. Notably, we have shown that the reactivity of the β-O-4 linkage in model compounds can be steered towards either cleavage or stabilization, depending on DES composition, demonstrating the advantage of the modular DES composition.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.