ArticleJournal of the American Chemical Society2021
The Ascent of Alkyne Metathesis to Strategy-Level Status.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 26 papers.
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Who cites it
26 citing papers in PubMed.
- A crystalline uranium Fischer-type carbyne.Nature chemistry · 2026Article
- Heavier Alkyne-NiAngewandte Chemie (International ed. in English) · 2026Article
- C─S Bond Metathesis Reactions: Concepts, Scope, and Mechanistic Insight.Chemistry, an Asian journal · 2026Review
- Reactivity of a dAngewandte Chemie (International ed. in English) · 2026Article
- Organophosphine-Promoted Decarbynylative Hydrocarbenylation of the Carbon-Carbon Triple Bond.Organic letters · 2026Article
- Toward vanadium-mediated alkyne metathesis.Chemical science · 2026Article
- Ring-Opening Alkyne Metathesis Polymerization Catalyzed by a Bench-Stable Rhenium Complex.Journal of the American Chemical Society · 2026Article
- Homoleptic Bismuth Alkynes: Isolable Reagents for Selective Alkynyl Radical Transfer.Angewandte Chemie (International ed. in English) · 2026Article
- Square-Planar Ruthenium Alkylidyne Complexes Undergo Stepwise Rather Than Concerted [2 + 2] Cycloadditions with Alkynes.Angewandte Chemie (International ed. in English) · 2026Article
- Collective Total Synthesis of a Unique Class of Liverworts-Derived Cembrane Diterpenoids.Angewandte Chemie (International ed. in English) · 2025Article
- Macrocyclic NHC Ligands in Hoveyda-Type Ru Alkene Metathesis Catalysts: Only Sterics?Inorganic chemistry · 2025Article
- Multifunctional chiral silanol ligands for enantioselective catalysis.Chemical science · 2025Article
- Tripodal Silanolate Ligands Expand [MoXJournal of the American Chemical Society · 2025Article
- Metallacyclobutadienes: Intramolecular Rearrangement from Kinetic to Thermodynamic Isomers.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Decreasing the Bond Order between Vanadium and Oxo Ligand to Form 3d Schrock Carbynes.Journal of the American Chemical Society · 2024Article
- Molybdenum(VI) Nitrido Complexes with Tripodal Silanolate Ligands. Structure and Electronic Character of an Unsymmetrical Dimolybdenum μ-Nitrido Complex Formed by Incomplete Nitrogen Atom Transfer.Inorganic chemistry · 2024Article
- Rhenium Alkyne Catalysis: Sterics Control the Reactivity.Inorganic chemistry · 2024Article
- Catalytic Reduction of Cyanide to Ammonia and Methane at a Mononuclear Fe Site.Journal of the American Chemical Society · 2024Article
- Diazene-Catalyzed Oxidative Alkyl Halide-Olefin Metathesis.Organic letters · 2024Article
- Total Synthesis of the Allenic Macrolide (+)-Archangiumide.Journal of the American Chemical Society · 2024Article
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Authors and funding
1 author.
Funding
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Abstract
For numerous enabling features and strategic virtues, contemporary alkyne metathesis is increasingly recognized as a formidable synthetic tool. Central to this development was the remarkable evolution of the catalysts during the past decades. Molybdenum alkylidynes carrying (tripodal) silanolate ligands currently set the standards; their functional group compatibility is exceptional, even though they comprise an early transition metal in its highest oxidation state. Their performance is manifested in case studies in the realm of dynamic covalent chemistry, advanced applications to solid-phase synthesis, a revival of transannular reactions, and the assembly of complex target molecules at sites, which one may not intuitively trace back to an acetylenic ancestor. In parallel with these innovations in material science and organic synthesis, new insights into the mode of action of the most advanced catalysts were gained by computational means and the use of unconventional analytical tools such as
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.