ArticleScience advances2021
Superstructured mesocrystals through multiple inherent molecular interactions for highly reversible sodium ion batteries.
Article in Science advances, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
19 citing papers in PubMed.
- Disease-Stage Synchronized Nanozyme Therapy for Polymicrobial Sepsis through Adaptive Catalytic and Immune Reprogramming.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Mitophagy-mediated immune evasion: Shared strategies of pathogens.Redox biology · 2026Review
- Noble-metal-free π-stacked metal-organic nanosheets featuring unidirectional electron transport channels for highly efficient electrocatalytic COChemical science · 2026Article
- Programmable next-generation supramolecular self-assembled materials as drug delivery systems.Bioactive materials · 2026Review
- Polyphenol-Derived Carbonaceous Frameworks with Multiscale Porosity for High-Power Electrochemical Applications.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Nanoengineered mitochondria for mitochondrial dysfunction and anti-aging interventions.Frontiers in aging · 2025Review
- Zinc finger-inspired peptide-metal-phenolic nanointerface enhances bone-implant integration under bacterial infection microenvironment through immune modulation and osteogenesis promotion.Bioactive materials · 2024Article
- Phenolic-enabled nanotechnology: a new strategy for central nervous system disease therapy.Journal of Zhejiang University. Science. B · 2024Review
- Facile and rapid fabrication of a novel 3D-printable, visible light-crosslinkable and bioactive polythiourethane for large-to-massive rotator cuff tendon repair.Bioactive materials · 2024Article
- A non-classical synthetic strategy for organic mesocrystals.Frontiers in chemistry · 2024Article
- Cobalt Oxide 2D Nanosheets Formed at a Polarized Liquid|Liquid Interface toward High-Performance Li-Ion and Na-Ion Battery Anodes.ACS applied materials & interfaces · 2023Article
- Advances in Electrochemical Energy Storage over Metallic Bismuth-Based Materials.Materials (Basel, Switzerland) · 2023Review
- Room-temperature phosphorescent materials derived from natural resources.Nature reviews. Chemistry · 2023Review
- Perspective and Prospects for Ordered Functional Materials.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Engineering Flexible Metal-Phenolic Networks with Guest Responsiveness via Intermolecular Interactions.Angewandte Chemie (International ed. in English) · 2023Article
- Site-Selective Coordination Assembly of Dynamic Metal-Phenolic Networks.Angewandte Chemie (International ed. in English) · 2022Article
- Imparting reusable and SARS-CoV-2 inhibition properties to standard masks through metal-organic nanocoatings.Journal of hazardous materials · 2022Article
- Supramolecular assemblies based on natural small molecules: Union would be effective.Materials today. Bio · 2022Review
- Intratumoral synthesis of transformable metal-phenolic nanoaggregates with enhanced tumor penetration and retention for photothermal immunotherapy.Theranostics · 2022Article
Corrections and comments
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Authors and funding
13 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Soft structures in nature, such as supercoiled DNA and proteins, can organize into complex hierarchical architectures through multiple noncovalent molecular interactions. Identifying new classes of natural building blocks capable of facilitating long-range hierarchical structuring has remained an elusive goal. We report the bottom-up synthesis of a hierarchical metal-phenolic mesocrystal where self-assembly proceeds on different length scales in a spatiotemporally controlled manner. Phenolic-based coordination complexes organize into supramolecular threads that assemble into tertiary nanoscale filaments, lastly packing into quaternary mesocrystals. The hierarchically ordered structures are preserved after thermal conversion into a metal-carbon hybrid framework and can impart outstanding performance to sodium ion batteries, which affords a capability of 72.5 milliampere hours per gram at an ultrahigh rate of 200 amperes per gram and a 90% capacity retention over 15,000 cycles at a current density of 5.0 amperes per gram. This hierarchical structuring of natural polyphenols is expected to find widespread applications.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.