Vapor Phase Synthesis of SnS Facilitated by Ligand-Driven "Launch Vehicle" Effect in Tin Precursors.

Ufuk Atamtürk, Veronika Brune, Shashank Mishra, Sanjay Mathur

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

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0 citing papers in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

4 authors.

Ufuk AtamtürkInstitute of Inorganic Chemistry, University of Cologne, Greinstraße 6, 50939 Cologne, Germany.

Veronika BruneInstitute of Inorganic Chemistry, University of Cologne, Greinstraße 6, 50939 Cologne, Germany.ORCID 0000-0001-5909-621X

Shashank MishraInstitut de Recherches sur la Catalyse et l'Environnement de Lyon (IRCELYON), Université Claude Bernard Lyon 1, CNRS, UMR 5256, 2 Avenue Albert Einstein, 69626 Villeurbanne, France.ORCID 0000-0003-2846-4221

Sanjay MathurInstitute of Inorganic Chemistry, University of Cologne, Greinstraße 6, 50939 Cologne, Germany.

Funding

Deutsche Forschungsgemeinschaft Will submit it later

6 · The paper itself

Abstract

Extraordinary low-temperature vapor-phase synthesis of SnS thin films from single molecular precursors is attractive over conventional high-temperature solid-state methods. Molecular-level processing of functional materials is accompanied by several intrinsic advantages such as precise control over stoichiometry, phase selective synthesis, and uniform substrate coverage. We report here on the synthesis of a new heteroleptic molecular precursor containing (i) a thiolate ligand forming a direct Sn-S bond, and (ii) a chelating O^N^N-donor ligand introducing a "launch vehicle"-effect into the synthesized compound, thus remarkably increasing its volatility. The newly synthesized tin compound [Sn(SBu

Indexed as

chemical vapor depositionsingle-crystal structuresingle-source precursortertiary butyl sulfidetin sulfide

Identifiers

PMID34500799

DOI10.3390/molecules26175367

PMCPMC8433875

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