Evidence map›Paper›PMID 34473484›Full record

ArticleJournal of the American Chemical Society2021

P

Gen Li, Steven P Miller, Alexander T Radosevich

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Article
  2. Article
  3. Tetrahedron · 2025
    Article
  4. Review
  5. Article
  6. Article
  7. Article
  8. Ligand-Enabled Disproportionation of 1,2-Diphenylhydrazine at a PAngewandte Chemie (International ed. in English) · 2022
    Article
  9. Chemoselective Primary Amination of Aryl Boronic Acids by PJournal of the American Chemical Society · 2022
    Article
  10. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Gen LiDepartment of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.ORCID 0000-0001-6857-0235
Steven P MillerDepartment of Process Research and Development, Merck & Co., Inc., West Point, Pennsylvania 19486, United States.
Alexander T RadosevichDepartment of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.ORCID 0000-0002-5373-7343

Funding

Synthetic Methods based on Biphilic Phosphorus CatalystsR01GM114547 · NIGMS · PENNSYLVANIA STATE UNIVERSITY, THE · PI Alexander T Radosevich · 2015 to 2026
$4.2M
NIGMS NIH HHS R01 GM114547
6 · The paper itself

Abstract

An organophosphorus-catalyzed method for the synthesis of unsymmetrical hydrazines by cross-selective intermolecular N-N reductive coupling is reported. This method employs a small ring phosphacycle (phosphetane) catalyst together with hydrosilane as the terminal reductant to drive reductive coupling of nitroarenes and anilines with good chemoselectivity and functional group tolerance. Mechanistic investigations support an autotandem catalytic reaction cascade in which the organophosphorus catalyst drives two sequential and mechanistically distinct reduction events via P

Indexed as

Aniline CompoundsCatalysisHydrazinesIndazolesNitrobenzenesOrganophosphorus CompoundsOxidation-ReductionAniline CompoundsHydrazinesIndazolesNitrobenzenesOrganophosphorus Compounds

Identifiers

PMID34473484
PMCPMC8454687

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.