ArticleAngewandte Chemie (International ed. in English)2021
Dissection of the Polar and Non-Polar Contributions to Aromatic Stacking Interactions in Solution.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
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- Circular Dichroism Reveals Positive Cooperativity through Compensatory Motion in Stepwise Cage Metalation.Inorganic chemistry · 2026Article
- Lignin Dissolution and Direct Ultrasmall-Lignin-Nanoparticle Formation in Acidic and Alkaline Deep Eutectic Solvents: A Molecular-Level Insight.Angewandte Chemie (International ed. in English) · 2025Article
- The effect of tethered bi-naphthyls on visible-light promoted alkene-alkene [2 + 2] cycloadditions.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2024Article
- Distinction and Quantification of Noncovalent Dispersive and Hydrophobic Effects.Molecules (Basel, Switzerland) · 2024Review
- Dispersion Interactions in Condensed Phases and inside Molecular Containers.Accounts of chemical research · 2023Article
- Context-Dependent Significance of London Dispersion.Accounts of chemical research · 2023Article
- The interplay between hydrogen and halogen bonding: substituent effects and their role in the hydrogen bond enhanced halogen bond.Chemical science · 2023Article
- Programmed guest confinementChemical science · 2023Article
- Substituent effects on aromatic interactions in water.Chemical science · 2023Article
- Dissection of the Polar and Non-Polar Contributions to Aromatic Stacking Interactions in Solution.Angewandte Chemie (International ed. in English) · 2021Article
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Authors and funding
5 authors.
Funding
Abstract
Aromatic stacking interactions have been a matter of study and debate due to their crucial role in chemical and biological systems. The strong dependence on orientation and solvent together with the relatively small interaction energies have made evaluation and rationalization a challenge for experimental and theoretical chemists. We have used a supramolecular cage formed by two tris(pyridylmethyl)amines units to build chemical Double Mutant Cycles (DMC) for the experimental measurement of the free energies of π-stacking interactions. Extrapolating the substituent effects to remove the contribution due to electrostatic interactions reveals that there is a substantial contribution to the measured stacking interaction energies which is due to non-polar interactions (-3 to -6 kJ mol
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