ArticleNature communications2021
Mechanochemical transformation of planar polyarenes to curved fused-ring systems.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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Who cites it
10 citing papers in PubMed.
- Mechanochemistry-Driven Borrowing Hydrogen Processes for Ru-Catalyzed N-Alkylation: A Pathway to Enhanced Sustainability and Efficiency.Angewandte Chemie (International ed. in English) · 2025Article
- Mechanochemical Synthesis and Electron Crystallography Characterization of van der Waals Lanthanoid 2D Metal-Organic Frameworks.Inorganic chemistry · 2025Article
- Ru(II)-Based Multitopic Hosts for Fullerene Binding: Impact of the Anion in the Recognition Process.Inorganic chemistry · 2025Article
- Mechanochemical synthesis of organoselenium compounds.Nature communications · 2024Article
- Tribochemical nanolithography: selective mechanochemical removal of photocleavable nitrophenyl protecting groups with 23 nm resolution at speeds of up to 1 mm sChemical science · 2023Article
- Mechanochemistry: New Tools to Navigate the Uncharted Territory of "Impossible" Reactions.ChemSusChem · 2022Review
- The Direct Mechanocatalytic Suzuki-Miyaura Reaction of Small Organic Molecules.Angewandte Chemie (International ed. in English) · 2022Article
- The Mechanochemical Synthesis and Activation of Carbon-Rich π-Conjugated Materials.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
- Acenaphthenoannulation Induced by the Dual Lewis Acidity of Alumina.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Beyond the Scholl reaction - one-step planarization and edge chlorination of nanographenes by mechanochemistry.RSC advances · 2021Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The transformation of planar aromatic molecules into π-extended non-planar structures is a challenging task and has not been realized by mechanochemistry before. Here we report that mechanochemical forces can successfully transform a planar polyarene into a curved geometry by creating new C-C bonds along the rim of the molecular structure. In doing so, mechanochemistry does not require inert conditions or organic solvents and provide better yields within shorter reaction times. This is illustrated in a 20-minute synthesis of corannulene, a fragment of fullerene C
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Registered trials
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