ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Multistimuli-Responsive [3]Dioxaphosphaferrocenophanes with Orthogonal Switches.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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The trial behind it
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Who cites it
7 citing papers in PubMed.
- Secondary Phosphines Bearing N-Heterocyclic Imine Groups: Polarity Umpolung of Highly Electron-Rich P-H Bonds.Inorganic chemistry · 2025Article
- Broadly Applicable Copper(I)-Catalyzed Alkyne Semihydrogenation and Hydrogenation of α,β-Unsaturated Amides Enabled by Bifunctional Iminopyridine Ligands.Journal of the American Chemical Society · 2025Article
- Syntheses, Characterization, and Redox Activity of Ferrocene-Containing Titanium Complexes.ACS omega · 2024Article
- Heterobimetallic Gold/Ruthenium Complexes Synthesized via Post-functionalization and Applied in Dual Photoredox Gold Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- From Stable PH-Ylides to α-Carbanionic Phosphines as Ligands for Zwitterionic Catalysts.Angewandte Chemie (International ed. in English) · 2022Article
- Tris(tetramethylguanidinyl)phosphine: The Simplest Non-ionic Phosphorus Superbase and Strongly Donating Phosphine Ligand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Multistimuli-Responsive [3]Dioxaphosphaferrocenophanes with Orthogonal Switches.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Novel multistimuli-responsive phosphine ligands comprising a redox-active [3]dioxaphosphaferrocenophane backbone and a P-bound imidazolin-2-ylidenamino entity that allows switching by protonation are reported. Investigation of the corresponding metal complexes and their redox behaviour are reported and show the sensitivity of the system towards protonation and metal coordination. The experimental findings are supported by DFT calculations. Protonation and oxidation events are applied in Rh-catalysed hydrosilylations and demonstrate a remarkable influence on reactivity and/or selectivity.
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Registered trials
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