Evidence map›Paper›PMID 34449200›Full record

ArticleEnvironmental science & technology2021

Surface Charge Measurements with Scanning Ion Conductance Microscopy Provide Insights into Nitrous Acid Speciation at the Kaolin Mineral-Air Interface.

Cheng Zhu, Gargi Jagdale, Adrien Gandolfo, Kristen Alanis, Rebecca Abney, Lushan Zhou, David Bish, Jonathan D Raff, Lane A Baker

Open access · greenAbstract read
In one paragraph

Article in Environmental science & technology, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
1.0field-weighted citation impact, top 28% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 14 citations in OpenAlex.

  1. Article
  2. Unveiling the underestimated direct emissions of nitrous acid (HONO).Proceedings of the National Academy of Sciences of the United States of America · 2023
    Article
  3. Charge Mapping ofAnalytical chemistry · 2023
    Article
  4. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 2 institutions in 1 country.

Cheng ZhuDepartment of Chemistry, Indiana University, Bloomington, Indiana 47401, United States.
Gargi JagdaleDepartment of Chemistry, Indiana University, Bloomington, Indiana 47401, United States.
Adrien GandolfoPaul H. O'Neill School of Public & Environmental Affairs, Indiana University, Bloomington, Indiana 47405, United States.
Kristen AlanisDepartment of Chemistry, Indiana University, Bloomington, Indiana 47401, United States.
Rebecca AbneyPaul H. O'Neill School of Public & Environmental Affairs, Indiana University, Bloomington, Indiana 47405, United States.
Lushan ZhouDepartment of Chemistry, Indiana University, Bloomington, Indiana 47401, United States.
David BishDepartment of Chemistry, Indiana University, Bloomington, Indiana 47401, United States.
Jonathan D RaffDepartment of Chemistry, Indiana University, Bloomington, Indiana 47401, United States.ORCID 0000-0002-2574-8061
Lane A BakerDepartment of Chemistry, Indiana University, Bloomington, Indiana 47401, United States.ORCID 0000-0001-5127-507X
Indiana University Bloomington · USUniversity of Georgia · US

Funding

Graduate Training Program in Quantitative and Chemical Biology at Indiana University BloomingtonT32GM131994 · NIGMS · TRUSTEES OF INDIANA UNIVERSITY · PI JARED C LEWIS · 2019 to 2026
$2.4M
Graduate Program in Quantitative and Chemical Biology at Indiana University BloomT32GM109825 · NIGMS · TRUSTEES OF INDIANA UNIVERSITY · PI GIEDROC, DAVID P. · 2014 to 2018
$926k
NIGMS NIH HHS T32 GM109825NIGMS NIH HHS T32 GM131994
6 · The paper itself

Abstract

Unique surface properties of aluminosilicate clay minerals arise from anisotropic distribution of surface charge across their layered structures. Yet, a molecular-level understanding of clay mineral surfaces has been hampered by the lack of analytical techniques capable of measuring surface charges at the nanoscale. This is important for understanding the reactivity, colloidal stability, and ion-exchange capacity properties of clay minerals, which constitute a major fraction of global soils. In this work, scanning ion conductance microscopy (SICM) is used for the first time to visualize the surface charge and topography of dickite, a well-ordered member of the kaolin subgroup of clay minerals. Dickite displayed a pH-independent negative charge on basal surfaces whereas the positive charge on edges increased from pH 6 to 3. Surface charges responded to malonate addition, which promoted dissolution/precipitation reactions. Results from SICM were used to interpret heterogeneous reactivity studies showing that gas-phase nitrous acid (HONO) is released from the protonation of nitrite at Al-OH

Indexed as

KaolinNitrous AcidClayMicroscopyMineralsClayKaolinMineralsNitrous Acidatmospheric chemistryclaymicroscopynitrous acidsurface charge

Identifiers

PMID34449200
PMCPMC9277718
OpenAlexW3195878962

What OpenQuestion holds

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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.