ReviewNanomaterials (Basel, Switzerland)2021
The Contribution of NMR Spectroscopy in Understanding Perovskite Stabilization Phenomena.
Review in Nanomaterials (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Imidazoanthraquinone Derivative as a Surface Passivator for Enhanced and Stable Perovskite Solar Cells.ACS omega · 2024Article
- Enhancing Photostability of Complex Lead Halides through Modification with Antibacterial Drug Octenidine.Materials (Basel, Switzerland) · 2023Article
- Solid-State Nuclear Magnetic Resonance of Triple-Cation Mixed-Halide Perovskites.The journal of physical chemistry letters · 2022Article
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2 authors.
Funding
Abstract
Although it has been exploited since the late 1900s to study hybrid perovskite materials, nuclear magnetic resonance (NMR) spectroscopy has only recently received extraordinary research attention in this field. This very powerful technique allows the study of the physico-chemical and structural properties of molecules by observing the quantum mechanical magnetic properties of an atomic nucleus, in solution as well as in solid state. Its versatility makes it a promising technique either for the atomic and molecular characterization of perovskite precursors in colloidal solution or for the study of the geometry and phase transitions of the obtained perovskite crystals, commonly used as a reference material compared with thin films prepared for applications in optoelectronic devices. This review will explore beyond the current focus on the stability of perovskites (3D in bulk and nanocrystals) investigated via NMR spectroscopy, in order to highlight the chemical flexibility of perovskites and the role of interactions for thermodynamic and moisture stabilization. The exceptional potential of the vast NMR tool set in perovskite structural characterization will be discussed, aimed at choosing the most stable material for optoelectronic applications. The concept of a double-sided characterization in solution and in solid state, in which the organic and inorganic structural components provide unique interactions with each other and with the external components (solvents, additives, etc.), for material solutions processed in thin films, denotes a significant contemporary target.
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