ArticleMaterials (Basel, Switzerland)2021
The Effect of Type-I Photoinitiators on the Kinetics of the UV-Induced Cotelomerization Process of Acrylate Monomers and Properties of Obtained Pressure-Sensitive Adhesives.
Article in Materials (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Functional Acrylic Resins Prepared via Photo-Induced Telomerization Using Tetrabromomethane as Telogen.Materials (Basel, Switzerland) · 2023Article
- Effect of Residue Acrylic Monomers in Synthesized Solvent-Free Photoreactive Pressure-Sensitive Adhesives on the Main Properties of Transfer Tapes Applied to Joining Wooden Elements.Materials (Basel, Switzerland) · 2023Article
- Influence of Photoinitiator Type and Curing Conditions on the Photocuring of Soft Polymer Network.Materials (Basel, Switzerland) · 2023Article
- Technologies for Joining and Forming Thin-Walled Structures in the Construction of Transportation Vehicles.Materials (Basel, Switzerland) · 2023Article
- Latest Advances in Highly Efficient Dye-Based Photoinitiating Systems for Radical Polymerization.Polymers · 2023Review
- Asphaltene-Stabilized Polyisobutylene Pressure-Sensitive Adhesives for Ultraviolet Protection and Surface Bonding.Materials (Basel, Switzerland) · 2023Article
- Self-Crosslinkable Pressure-Sensitive Adhesives from Silicone-(Meth)acrylate Telomer Syrups.Materials (Basel, Switzerland) · 2022Article
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Authors and funding
4 authors.
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No grant is acknowledged in the PubMed record.
Abstract
A new method of solvent-free acrylic pressure-sensitive adhesives (PSAs) based on UV-induced cotelomerization products was presented. The key acrylic monomers (i.e., n-butyl acrylate and acrylic acid) with copolymerizable photoinitiator 4-acrylooxybenzophenone in the presence of a selected chain transfer agent (tetrabromomethane, TBM) were used in the UV-cotelomerization process. Moreover, two kinds of UV-photoinitiators (α-hydroxyalkylphenones, HPs and acylphosphine oxides, APOs) were tested. Photo-DSC, viscosity, thermogravimetric, and GPC measurements for cotelomers were performed. The kinetics study revealed that the systems with APOs, especially Omnirad 819 and Omnirad TPO, were characterized by a much higher reaction rate and greater initiation efficiency than HPs systems were. Additionally, the APO-based syrups exhibited a higher solid content (ca. 60-96 wt%), a higher dynamic viscosity (5-185 Pa·s), but slightly lower molecular weights (M
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