ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Photo-Induced Ruthenium-Catalyzed C-H Benzylations and Allylations at Room Temperature.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Arene Ruthenium(II) Carboxylates for C─H Alkylations and Arylations at Near Room Temperature.Angewandte Chemie (International ed. in English) · 2025Article
- Photo-induced ruthenium-catalyzed alkene C-H-arylation at room temperature.Chemical communications (Cambridge, England) · 2025Article
- Bis-Cycloruthenated Complexes in Visible Light-Induced C-H Alkylation with Epoxides.Journal of the American Chemical Society · 2025Article
- Photocatalytic regioselective C-H bond functionalizations in arenes.Chemical science · 2025Review
- Photoinduced C-H arylation of 1,3-azolesChemical science · 2024Article
- Photoredox-Catalyzed Decarboxylative Cross-Coupling Reaction to Synthesis Unsymmetrical Diarylmethanes.Molecules (Basel, Switzerland) · 2024Article
- Silver-Free C-H Activation: Strategic Approaches towards Realizing the Full Potential of C-H Activation in Sustainable Organic Synthesis.Angewandte Chemie (International ed. in English) · 2022Review
- Ru(II)-Catalyzed Hydroarylation of in situ Generated 3,3,3-Trifluoro-1-propyne by C-H Bond Activation: A Facile and Practical Access to β-Trifluoromethylstyrenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Visible-Light-Induced, Single-Metal-Catalyzed, Directed C-H Functionalization: Metal-Substrate-Bound Complexes as Light-Harvesting Agents.Angewandte Chemie (International ed. in English) · 2022Review
- Reductant-Free Cross-Electrophile Synthesis of Di(hetero)arylmethanes by Palladium-Catalyzed Desulfinative C-C Coupling.Angewandte Chemie (International ed. in English) · 2022Article
- Photo-Induced Ruthenium-Catalyzed C-H Benzylations and Allylations at Room Temperature.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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Authors and funding
4 authors.
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Abstract
The ruthenium-catalyzed synthesis of diarylmethane compounds was realized under exceedingly mild photoredox conditions without the use of exogenous photocatalysts. The versatility and robustness of the ruthenium-catalyzed C-H benzylation was reflected by an ample scope, including multifold C-H functionalizations, as well as transformable pyrazoles, imidates and sensitive nucleosides. Mechanistic studies were indicative of a photoactive cyclometalated ruthenium complex, which also enabled versatile C-H allylations.
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