ArticleThe journal of physical chemistry letters2021
Reversal of the Temperature Dependence of Hydrophobic Hydration in Supercooled Water.
Article in The journal of physical chemistry letters, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed, 5 citations in OpenAlex.
- Gaussian and Non-Gaussian Solvent Density Fluctuations within Solute Cavities in a Water-like Solvent.Journal of chemical theory and computation · 2024Article
- Water's Unusual Thermodynamics in the Realm of Physical Chemistry.The journal of physical chemistry. B · 2022Review
- Crustwater: Modeling Hydrophobic Solvation.The journal of physical chemistry. B · 2022Article
Corrections and comments
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Authors and funding
1 author at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Using simulations and theory, we examine the enthalpy and entropy of hydrophobic hydration which exhibit minima in supercooled water, contrasting with the monotonically increasing temperature dependence traditionally ascribed to these properties. The enthalpy/entropy minima are marked by a negative to positive sign change in the heat capacity at a size-dependent reversal temperature. A Gaussian fluctuation theory accurately captures the reversal temperature, tracing it to water's distinct thermal expansivity and compressibility influenced by its metastable liquid-liquid critical point.
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Registered trials
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