Evidence map›Paper›PMID 34431660›Full record

ArticleInorganic chemistry2021

High Magnetic Anisotropy of a Square-Planar Iron-Carbene Complex.

Brett M Hakey, Dylan C Leary, Jin Xiong, Caleb F Harris, Jonathan M Darmon, Jeffrey L Petersen, John F Berry, Yisong Guo, Carsten Milsmann

Abstract read
In one paragraph

Article in Inorganic chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Article
  6. Fine Structure and the Huge Zero-Field Splitting in NiMolecules (Basel, Switzerland) · 2022
    Article
  7. Article
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Brett M HakeyC. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, West Virginia 26506, United States.ORCID https://orcid.org/0000-0003-2571-2672
Dylan C LearyC. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, West Virginia 26506, United States.ORCID https://orcid.org/0000-0003-0588-8267
Jin XiongDepartment of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States.ORCID https://orcid.org/0000-0001-7443-0554
Caleb F HarrisDepartment of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, United States.ORCID https://orcid.org/0000-0002-6844-8923
Jonathan M DarmonDepartment of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.ORCID https://orcid.org/0000-0002-2387-2958
Jeffrey L PetersenC. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, West Virginia 26506, United States.
John F BerryDepartment of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, United States.ORCID https://orcid.org/0000-0002-6805-0640
Yisong GuoDepartment of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States.ORCID https://orcid.org/0000-0002-4132-3565
Carsten MilsmannC. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, West Virginia 26506, United States.ORCID https://orcid.org/0000-0002-9249-5199

Funding

Elucidate Mechanisms of Quinolone Alkaloid Biosynthesis via Iron(II)/2-Oxoglutarate Dependent Enzymes: Diverse, but Controlled ReactivityR01GM125924 · NIGMS · CARNEGIE-MELLON UNIVERSITY · PI Yisong Guo · 2018 to 2026
$3.3M
NIGMS NIH HHS R01 GM125924
6 · The paper itself

Abstract

Among Earth-abundant catalyst systems, iron-carbene intermediates that perform C-C bond forming reactions such as cyclopropanation of olefins and C-H functionalization via carbene insertion are rare. Detailed descriptions of the possible electronic structures for iron-carbene bonds are imperative to obtain better mechanistic insights and enable rational catalyst design. Here, we report the first square-planar iron-carbene complex (

Identifiers

PMID34431660
PMCPMC9106389

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.