Evidence map›Paper›PMID 34422448›Full record

ArticleACS catalysis2021

Visible Light-Induced Pd-Catalyzed Alkyl-Heck Reaction of Oximes.

Nikita Kvasovs, Valeriia Iziumchenko, Vitalii Palchykov, Vladimir Gevorgyan

Abstract read
In one paragraph

Article in ACS catalysis, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.

0numbers the graph read from it
0cells of the map it votes in
20citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

20 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Illuminating Palladium Catalysis.Accounts of chemical research · 2025
    Article
  5. Recent Advances in Visible Light Induced Palladium Catalysis.Angewandte Chemie (International ed. in English) · 2024
    Review
  6. Article
  7. Article
  8. Article
  9. PhotoinducedJACS Au · 2023
    Article
  10. Article
  11. Article
  12. Article
  13. Palladium Hydride-Enabled Hydroalkenylation of Strained Molecules.Journal of the American Chemical Society · 2022
    Article
  14. Article
  15. Accessing IllusiveOrganic letters · 2022
    Article
  16. C2-ketonylation of carbohydratesChemical science · 2022
    Article
  17. Article
  18. Review
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Nikita KvasovsDepartment of Chemistry and Biochemistry, The University of Texas at Dallas, Richardson, Texas 75080-3021, United States.
Valeriia IziumchenkoDepartment of Chemistry and Biochemistry, The University of Texas at Dallas, Richardson, Texas 75080-3021, United States.
Vitalii PalchykovDepartment of Chemistry and Biochemistry, The University of Texas at Dallas, Richardson, Texas 75080-3021, United States.
Vladimir GevorgyanDepartment of Chemistry and Biochemistry, The University of Texas at Dallas, Richardson, Texas 75080-3021, United States.ORCID 0000-0002-7836-7596

Funding

Transition Metal-Radical Hybrid Methods for Organic SynthesisR01GM120281 · NIGMS · UNIVERSITY OF TEXAS DALLAS · PI GEVORGYAN, VLADIMIR · 2017 to 2024
$2.5M
NIGMS NIH HHS R01 GM120281
6 · The paper itself

Abstract

A visible light-induced palladium-catalyzed oxidative C-H alkylation of oximes has been developed. This mild protocol allows for an efficient atom economical C-C bond construction of alkyl-substituted oximes. A broad range of primary, secondary, and tertiary alkyl bromides and iodides, as well as a range of different formaldoximes, can efficiently undergo this transformation. The method features visible light-induced generation of nucleophilic hybrid alkyl Pd radical intermediates, which upon radical addition at the imine moiety and a subsequent

Indexed as

alkylationHeck reactionlight-inducedoximepalladiumradical

Identifiers

PMID34422448
PMCPMC8372551

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.