ArticleAngewandte Chemie (International ed. in English)2021
Catalyst-Controlled Stereoselective Barton-Kellogg Olefination.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed, 20 citations in OpenAlex.
- Control over stereogenic centres beyond tetracoordination.Chemical science · 2026Review
- Barton-Kellogg Olefination of (CFJACS Au · 2025Article
- Catalyst control over pentavalent stereocentres.Nature communications · 2023Article
- Diastereodivergent Catalysis.JACS Au · 2023Review
- Photocatalytic deracemisation of cobalt(III) complexes with fourfold stereogenicity.Chemical communications (Cambridge, England) · 2022Article
- Synthesis of cis-thiiranes as diastereoselective access to epoxide congeners via 4π-electrocyclization of thiocarbonyl ylides.Nature communications · 2022Article
- Direct Stereodivergent Olefination of Carbonyl Compounds with Sulfur Ylides.Journal of the American Chemical Society · 2022Article
- Novel Copper(II) Complexes with Dipinodiazafluorene Ligands: Synthesis, Structure, Magnetic and Catalytic Properties.Molecules (Basel, Switzerland) · 2022Article
- Catalyst-Controlled Stereoselective Barton-Kellogg Olefination.Angewandte Chemie (International ed. in English) · 2021Article
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Overcrowded alkenes are expeditiously prepared by the versatile Barton-Kellogg olefination and have remarkable applications as functional molecules owing to their unique stereochemical features. The induced stereodynamics thereby enable the controlled motion of molecular switches and motors, while the high configurational stability prevents undesired isomeric scrambling. Bistricyclic aromatic enes are prototypical overcrowded alkenes with outstanding stereochemical properties, but their stereocontrolled preparation was thus far only feasible in stereospecific reactions and with chiral auxiliaries. Herein we report that direct catalyst control is achieved by a stereoselective Barton-Kellogg olefination with enantio- and diastereocontrol for various bistricyclic aromatic enes. Using Rh
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