ArticleAngewandte Chemie (International ed. in English)2021
Bright Luminescence in Three Phases-A Combined Synthetic, Spectroscopic and Theoretical Approach.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed.
- Morphological Control of Aurophilic Chains of Gold(I) Dithiolate Dimers With Alkali and Alkali Earth Cations.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Hetero-bimetallic Lanthanide-Coinage Metal Compounds Featuring Possible Metal-Metal Interactions in the Excited State.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Bright Luminescence in Three Phases-A Combined Synthetic, Spectroscopic and Theoretical Approach.Angewandte Chemie (International ed. in English) · 2021Article
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Authors and funding
9 authors.
Funding
Abstract
Combining phase-dependent photoluminescence (PL) measurements and quantum chemical calculations is a powerful approach to help understand the influence of the molecular surroundings on the PL properties. Herein, a phosphine functionalized amidinate was used to synthesize a recently presented bimetallic gold complex, featuring an unusual charge separation. The latter was subsequently used as metalloligand to yield heterotetrametallic complexes with an Au-M-M-Au "molecular wire" arrangement (M=Cu, Ag, Au) featuring metallophilic interactions. All compounds show bright phosphorescence in the solid state, also at ambient temperature. The effect of the molecular environment on the PL was studied in detail for these tetrametallic complexes by comparative measurements in solution, in the solid state and in the gas phase and contrasted to time-dependent density functional theory computations.
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