Evidence map›Paper›PMID 34410708›Full record

ArticleJournal of the American Chemical Society2021

Nickel-Catalyzed Enantioselective Synthesis of Pre-Differentiated Homoallylic

Thomas Q Davies, John J Murphy, Maxime Dousset, Alois Fürstner

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Enantioselective Synthesis ofJournal of the American Chemical Society · 2024
    Article
  3. Article
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Thomas Q DaviesMax-Planck-Institut für Kohlenforschung, 45470 Mülheim/Ruhr, Germany.ORCID 0000-0003-1054-1161
John J MurphyMax-Planck-Institut für Kohlenforschung, 45470 Mülheim/Ruhr, Germany.ORCID 0000-0001-8411-9540
Maxime DoussetMax-Planck-Institut für Kohlenforschung, 45470 Mülheim/Ruhr, Germany.
Alois FürstnerMax-Planck-Institut für Kohlenforschung, 45470 Mülheim/Ruhr, Germany.ORCID 0000-0003-0098-3417

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Nickel catalysis allied with cyclodiphosphazane or VAPOL-derived phosphoramidite ligands provides selective access to monoprotected vicinal diols by reductive coupling of dienol ethers and aldehydes. The observed regioselectivity is unprecedented, in that the diene reacts at the least nucleophilic and most hindered C atom that is attached to the oxygen substituent rather than at the terminal position. Notably, both

Identifiers

PMID34410708
PMCPMC8414482

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.