ArticleAngewandte Chemie (International ed. in English)2021
Anodic Dehydrogenative Cyanamidation of Thioethers: Simple and Sustainable Synthesis of N-Cyanosulfilimines.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Article
- Electrochemical oxidation enables aromatic C-H amination with dual mechanisms.Nature synthesis · 2026Article
- Chemoselective Electrochemical Coupling of Thioethers and Primary Amines for Accessing Sulfilimines and Sulfoximines.Journal of the American Chemical Society · 2025Article
- Tailoring the selective generation of oxidative organic radicals for toxic-by-product-free water decontamination.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Article
- Controlling Selectivity in Shuttle Hetero-difunctionalization Reactions: Electrochemical Transfer Halo-thiolation of Alkynes.Angewandte Chemie (International ed. in English) · 2023Article
- Article
- Counter Electrode Reactions-Important Stumbling Blocks on the Way to a Working Electro-organic Synthesis.Angewandte Chemie (International ed. in English) · 2022Review
- Robust and Self-Cleaning Electrochemical Production of Periodate.ChemSusChem · 2022Article
- Anodic Dehydrogenative Cyanamidation of Thioethers: Simple and Sustainable Synthesis of N-Cyanosulfilimines.Angewandte Chemie (International ed. in English) · 2021Article
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Authors and funding
2 authors.
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Abstract
A novel and very simple to perform electrochemical approach for the synthesis of several N-cyanosulfilimines in good to excellent yields was established. This method provides access to biologically relevant sulfoximines by consecutive oxidation using electro-generated periodate. This route can be easily scaled-up to gram quantities. The S,N coupling is carried out at an inexpensive carbon anode by direct oxidation of sulfide. Therefore, the designed process is atom economic and represents a new "green route" for the synthesis of sulfilimines and sulfoximines.
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Registered trials
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