Evidence map›Paper›PMID 34405513›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Ball-Milling-Enabled Reactivity of Manganese Metal*.

William I Nicholson, Joseph L Howard, Giuseppina Magri, Alex C Seastram, Adam Khan, Robert R A Bolt, Louis C Morrill, Emma Richards, Duncan L Browne

Open access · hybridAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.

0numbers the graph read from it
0cells of the map it votes in
11citing papers in PubMed
3.5field-weighted citation impact, top 6% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

11 citing papers in PubMed, 54 citations in OpenAlex.

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  11. Ball-Milling-Enabled Reactivity of Manganese Metal*.Angewandte Chemie (International ed. in English) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 2 institutions in 1 country.

William I NicholsonSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK.
Joseph L HowardSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK.
Giuseppina MagriSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK.ORCID 0000-0003-3224-6227
Alex C SeastramSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK.
Adam KhanSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK.
Robert R A BoltDepartment of Pharmaceutical and Biological Chemistry, University College London (UCL), School of Pharmacy, 29-39 Brunswick Square, London, WC1N 1AX, UK.
Louis C MorrillSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK.ORCID 0000-0002-6453-7531
Emma RichardsSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK.ORCID 0000-0001-6691-2377
Duncan L BrowneDepartment of Pharmaceutical and Biological Chemistry, University College London (UCL), School of Pharmacy, 29-39 Brunswick Square, London, WC1N 1AX, UK.ORCID 0000-0002-8604-229X
Cardiff University · GBUniversity College London · GB

Funding

engineering and physical sciences research council EP/R006504/1engineering and physical sciences research council EP/R513003/1
6 · The paper itself

Abstract

Efforts to generate organomanganese reagents under ball-milling conditions have led to the serendipitous discovery that manganese metal can mediate the reductive dimerization of arylidene malonates. The newly uncovered process has been optimized and its mechanism explored using CV measurements, radical trapping experiments, EPR spectroscopy, and solution control reactions. This unique reactivity can also be translated to solution whereupon pre-milling of the manganese is required.

Indexed as

ball millingelectron paramagnetic spectroscopymanganeseorganometallicsreductive coupling

Identifiers

PMID34405513
PMCPMC8596600
OpenAlexW3195318739

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.