Evidence map›Paper›PMID 34405506›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Generation of α-Boryl Radicals by H

Shicheng Shi, Farbod Salahi, Hunter B Vibbert, Maleeha Rahman, Scott A Snyder, Jack R Norton

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Borylcyclopropanes: Synthetic Strategies and Applications.Angewandte Chemie (International ed. in English) · 2026
    Review
  2. Article
  3. Article
  4. Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Shicheng ShiDepartment of Chemistry, Columbia University, 3000 Broadway, New York, NY, 10027, USA.ORCID http://orcid.org/0000-0001-8124-9235
Farbod SalahiDepartment of Chemistry, University of Chicago, 5735 South Ellis Avenue, Chicago, IL, 60637, USA.ORCID http://orcid.org/0000-0003-3577-6813
Hunter B VibbertDepartment of Chemistry, Columbia University, 3000 Broadway, New York, NY, 10027, USA.ORCID http://orcid.org/0000-0001-9591-7150
Maleeha RahmanDepartment of Chemistry, Barnard College, 3009 Broadway, New York, NY, 10027, USA.
Scott A SnyderDepartment of Chemistry, University of Chicago, 5735 South Ellis Avenue, Chicago, IL, 60637, USA.ORCID http://orcid.org/0000-0003-3594-8769
Jack R NortonDepartment of Chemistry, Columbia University, 3000 Broadway, New York, NY, 10027, USA.ORCID http://orcid.org/0000-0003-1563-9555

Funding

Catalysis of Tin-Free Radical Reactions Under H2R01GM124295 · NIGMS · COLUMBIA UNIV NEW YORK MORNINGSIDE · PI NORTON, JACK R · 2017 to 2020
$1.5M
NIGMS NIH HHS R01 GM124295NIH HHS R01GM124295
6 · The paper itself

Abstract

Carbon-centered radicals can be stabilized by delocalization of their spin density into the vacant p orbital of a boron substituent. α-Vinyl boronates, in particular pinacol (Bpin) derivatives, are excellent hydrogen atom acceptors. Under H

Indexed as

cycloisomerizationhydrogen atom transferradical cyclizationα-boryl radical

Identifiers

PMID34405506
PMCPMC8582025

What OpenQuestion holds

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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.