ArticleNature communications2021
Dual metal nanoparticles within multicompartmentalized mesoporous organosilicas for efficient sequential hydrogenation.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Biomimetic Strategy to Fabricate Hierarchically Porous Zein Microreactors With a Hydrophobic Core-Hydrophilic Shell Architecture.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Nanomaterial Integration at Liquid-Liquid Interfaces for Green Catalysis.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Chitosan coated multifunctional NiFe₂O₄ nanocomposites as a promising candidate for biomedical applications.Naunyn-Schmiedeberg's archives of pharmacology · 2026Article
- Paddle-like self-stirring nanoreactors with multi-chambered mesoporous branches for enhanced dual-dynamic cascade reactions.Nature nanotechnology · 2025Article
- Important role of HNature communications · 2025Article
- Understanding the chemistry of mesostructured porous nanoreactors.Nature reviews. Chemistry · 2024Review
- Colloidal Templating in Catalyst Design for Thermocatalysis.Journal of the American Chemical Society · 2024Review
- Organic Molecular Glues to Design Three-Dimensional Cubic Nano-assemblies of Magnetic Nanoparticles.Chemistry of materials : a publication of the American Chemical Society · 2024Article
- Selective hydrodeoxygenation of α, β-unsaturated carbonyl compounds to alkenes.Nature communications · 2024Article
- Reactant enrichment in hollow void of Pt NPs@MnOx nanoreactors for boosting hydrogenation performance.National science review · 2023Article
- Sequential hydrogenation of nitroaromatics to alicyclic aminesRSC advances · 2023Article
- Remodeling nanodroplets into hierarchical mesoporous silica nanoreactors with multiple chambers.Nature communications · 2022Article
- Oriented self-assembly of metal-organic frameworks driven by photoinitiated monomer polymerization.RSC advances · 2022Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Controlling localization of multiple metal nanoparticles on a single support is at the cutting edge of designing cascade catalysts, but is still a scientific and technological challenge because of the lack of nanostructured materials that can not only host metal nanoparticles in different sub-compartments but also enable efficient molecular transport between different metals. Herein we report a multicompartmentalized mesoporous organosilica with spatially separated sub-compartments that are connected by short nanochannels. Such a unique structure allows co-localization of Ru and Pd nanoparticles in a nanoscale proximal fashion. The so designed cascade catalyst exhibits an order of magnitude activity enhancement in the sequential hydrogenation of nitroarenes to cyclohexylamines compared with its mono/bi-metallic counterparts. Crucially, an interesting phenomenon of neighboring metal-assisted hydrogenation via hydrogen spillover is observed, contributing to the significant enhancement in catalytic efficiency. The multicompartmentalized architectures along with the revealed mechanism of accelerated hydrogenation provide vast opportunity for designing efficient cascade catalysts.
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Registered trials
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