ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Low-Valent Germanylidene Anions: Efficient Single-Site Nucleophiles for Activation of Small Molecules.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed, 20 citations in OpenAlex.
- Activation of Small Molecules by Heavier Analogs of Cyclic(Alkyl)(Amino)Carbenes (CAACs): A DFT Study.Inorganic chemistry · 2026Article
- Isolation and reactivity of an alkyl-substituted germanium(I) radical anion.Nature communications · 2026Article
- Attempts toward a Silyl-Stabilized Dicoordinate Borylene: Insertion of Carbon Dioxide into the B-Si Bond.Organometallics · 2025Article
- Synthesis of Genuine Germenyl Lithiums and the First Persistent Germenyl Radicals.Angewandte Chemie (International ed. in English) · 2022Article
- Low-Valent Germanylidene Anions: Efficient Single-Site Nucleophiles for Activation of Small Molecules.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
Rare mononuclear and helical chain low-valent germanylidene anions supported by cyclic (alkyl)(amino)carbene and hypermetallyl ligands were synthesised by stepwise reduction from corresponding germylene precursors via stable and isolable germanium radicals. The electronic structures of the anions can be described with ylidene and ylidone resonance forms with the Ge-C π-electrons capable of binding even weak electrophiles. The germanylidene anions reacted with CO
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Registered trials
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