Evidence map›Paper›PMID 34399005›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Sustainable Pd(OAc)

Alexios G Stamoulis, Peng Geng, Michael A Schmidt, Martin D Eastgate, Alina Borovika, Kenneth J Fraunhoffer, Shannon S Stahl

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Alexios G StamoulisDepartment of Chemistry, University of Wisconsin-Madison, Madison, WI, 53706, USA.ORCID 0000-0003-4886-0512
Peng GengChemical Process Development, Bristol-Myers Squibb, New Brunswick, New Jersey, 08903, USA.ORCID 0000-0002-8749-4626
Michael A SchmidtChemical Process Development, Bristol-Myers Squibb, New Brunswick, New Jersey, 08903, USA.ORCID 0000-0002-4880-2083
Martin D EastgateChemical Process Development, Bristol-Myers Squibb, New Brunswick, New Jersey, 08903, USA.ORCID 0000-0002-6487-3121
Alina BorovikaChemical Process Development, Bristol-Myers Squibb, New Brunswick, New Jersey, 08903, USA.ORCID 0000-0002-0626-028X
Kenneth J FraunhofferChemical Process Development, Bristol-Myers Squibb, New Brunswick, New Jersey, 08903, USA.ORCID 0000-0002-1771-3416
Shannon S StahlDepartment of Chemistry, University of Wisconsin-Madison, Madison, WI, 53706, USA.ORCID 0000-0002-9000-7665

Funding

Palladium-Catalyzed Aerobic Dehydrogenation of Carbon-Carbon BondsR01GM100143 · NIGMS · UNIVERSITY OF WISCONSIN-MADISON · PI STAHL, SHANNON S · 2012 to 2019
$2.5M
ENANTIOSELECTIVE TRIPLET SENSITIZATION REACTIONSR01GM127545 · NIGMS · UNIVERSITY OF WISCONSIN-MADISON · PI YOON, TEHSHIK P · 2018 to 2021
$1.2M
bristol-myers squibbdivision of chemistry CHE-1953926national science foundation CHE-1048642NIGMS NIH HHS R01 GM100143NIGMS NIH HHS R01 GM127545NIH HHS R01GM100143NIH HHS R01GM127545
6 · The paper itself

Abstract

The 1,4-diacyloxylation of 1,3-cyclohexadiene (CHD) affords valuable stereochemically defined scaffolds for natural product and pharmaceutical synthesis. Existing cis-selective diacyloxylation protocols require superstoichiometric quantities of benzoquinone (BQ) or MnO

Indexed as

AcetatesBenzoatesCatalysisCyclohexenesHydroquinonesOrganometallic CompoundsPalladiumStereoisomerism1,3-cyclohexadieneAcetatesBenzoatesCyclohexenesHydroquinonesOrganometallic CompoundsPalladiumpalladium(II) acetatedifunctionalizationhomogeneous catalysisoxidationpalladiumsynthetic methods

Identifiers

PMID34399005
PMCPMC8511170

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.