ArticleJournal of the American Chemical Society2021
Cascade Dynamics of Multiple Molecular Rotors in a MOF: Benchmark Mobility at a Few Kelvins and Dynamics Control by CO
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
9 citing papers in PubMed.
- Turn-on luminescence from molecular rotor realignment in metal-organic framework thin films.Nature communications · 2026Article
- Targeted Dealumination via In Situ Activation of Persulfate in Size-Selective Zeolite Channels.The journal of physical chemistry letters · 2025Article
- Unveiling Local Dynamics of a Triptycene-Based Porous Polymer by Solid-State NMR.Macromolecules · 2024Article
- Long-Range and Coupled Rotor Dynamics in NOThe journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Unraveling Thermally Regulated Gating Mechanisms in TPT Pore-Partitioned MOF-74: A Computational Endeavor.Chemistry of materials : a publication of the American Chemical Society · 2024Article
- Benzothiadiazole-based rotation and possible antipolar order in carboxylate-based metal-organic frameworks.Communications chemistry · 2023Article
- Functional dynamics in framework materials.Communications chemistry · 2023Review
- Accounts of applied molecular rotors and rotary motors: recent advances.Nanoscale advances · 2023Review
- Optimization of Pore-Space-Partitioned Metal-Organic Frameworks Using the Bioisosteric Concept.Journal of the American Chemical Society · 2022Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Achieving sophisticated juxtaposition of geared molecular rotors with negligible energy-requirements in solids enables fast yet controllable and correlated rotary motion to construct switches and motors. Our endeavor was to realize multiple rotors operating in a MOF architecture capable of supporting fast motional regimes, even at extremely cold temperatures. Two distinct ligands, 4,4'-bipyridine (bipy) and bicyclo[1.1.1]pentanedicarboxylate (BCP), coordinated to Zn clusters fabricated a pillar-and-layer 3D array of orthogonal rotors. Variable temperature XRD,
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.