Evidence map›Paper›PMID 34387926›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021

Stereospecific on-Surface Cyclodehydrogenation of Bishelicenes: Preservation of Handedness from Helical to Planar Chirality.

Bahaaeddin Irziqat, Aleksandra Cebrat, Miloš Baljozović, Kévin Martin, Manfred Parschau, Narcis Avarvari, Karl-Heinz Ernst

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Bahaaeddin IrziqatMolecular Surface Science and Coating Technology Laboratory, Empa, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, 8600, Dübendorf, Switzerland.
Aleksandra CebratMolecular Surface Science and Coating Technology Laboratory, Empa, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, 8600, Dübendorf, Switzerland.
Miloš BaljozovićMolecular Surface Science and Coating Technology Laboratory, Empa, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, 8600, Dübendorf, Switzerland.ORCID http://orcid.org/0000-0002-2728-8142
Kévin MartinMOLTECH-Anjou UMR 6200, CNRS, UNIV Angers, 2 bd Lavoisier, 49045, Angers Cedex, France.
Manfred ParschauMolecular Surface Science and Coating Technology Laboratory, Empa, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, 8600, Dübendorf, Switzerland.
Narcis AvarvariMOLTECH-Anjou UMR 6200, CNRS, UNIV Angers, 2 bd Lavoisier, 49045, Angers Cedex, France.ORCID http://orcid.org/0000-0001-9970-4494
Karl-Heinz ErnstMolecular Surface Science and Coating Technology Laboratory, Empa, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, 8600, Dübendorf, Switzerland.ORCID http://orcid.org/0000-0002-2077-4922

Funding

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung 182082
6 · The paper itself

Abstract

Flattening helices while keeping the handedness: On-surface cyclodehydrogenation of bishelicene enantiomers leads stereospecifically to (M,M) and (P,P) chiral planar polyaromatic hydrocarbons. This is followed by their homochiral aggregation into a 2D conglomerate. Thermally induced cyclodehydrogenation proceeds stereospecifically to chiral, planar coronocoronene. Such a reaction is a special example of topochemistry in which enantiospecific conversion is supported by the alignment of the reactant by the surface.

Indexed as

chiralityhelicenespolyaromatic hydrocarbonsscanning tunneling microscopysurface chemistry

Identifiers

PMID34387926
PMCPMC8518606

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.