Inverse kinetic isotope effects in the charge transfer reactions of ammonia with rare gas ions.

A Tsikritea, K Park, P Bertier, J Loreau, T P Softley, B R Heazlewood

Abstract read

In one paragraph

Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it

0cells of the map it votes in

3citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

Spatial and Temporal Detection of Ions Ejected from Coulomb Crystals.The journal of physical chemistry. A · 2024
Article
Reply to: Inconsistent kinetic isotope effect in ammonia charge exchange reaction measured in a Coulomb crystal and in a selected-ion flow tube.Nature communications · 2022
Article
Charge Transfer Reactions between Water Isotopologues and KrACS physical chemistry Au · 2022
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

A TsikriteaDepartment of Chemistry, University of Oxford, Physical and Theoretical Chemistry South Parks Road Oxford OX1 3QZ UK.

K ParkDepartment of Chemistry, University of Oxford, Physical and Theoretical Chemistry South Parks Road Oxford OX1 3QZ UK.

P BertierDepartment of Chemistry, University of Oxford, Physical and Theoretical Chemistry South Parks Road Oxford OX1 3QZ UK.

J LoreauKU Leuven, Department of Chemistry Celestijnenlaan 200F B-3001 Leuven Belgium.ORCID https://orcid.org/0000-0002-6142-1509

T P SoftleySchool of Chemistry, University of Birmingham Edgbaston B15 2TT UK.

B R HeazlewoodDepartment of Physics, University of Liverpool Liverpool L69 7ZE UK b.r.heazlewood@liverpool.ac.uk.ORCID https://orcid.org/0000-0003-2073-4004

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

In the absence of experimental data, models of complex chemical environments rely on predicted reaction properties. Astrochemistry models, for example, typically adopt variants of capture theory to estimate the reactivity of ionic species present in interstellar environments. In this work, we examine astrochemically-relevant charge transfer reactions between two isotopologues of ammonia, NH

Identifiers

PMID34377395

DOI10.1039/d1sc01652k

PMCPMC8317658

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.