ArticleChemical science2021
Cyclic monoterpenes trapped in a polyaromatic capsule: unusual selectivity, isomerization, and volatility suppression.
Article in Chemical science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 24 citations in OpenAlex.
- Coordination sphere interactions drive isomer selection in heteroleptic Pd(ii) cages with low-symmetry ligands.Chemical science · 2025Article
- Discrimination of Perfluorinated Arenes/Alkanes by Modulable Polyaromatic Capsules.Journal of the American Chemical Society · 2025Article
- Helicity control of a polyaromatic coordination capsule through stereoselective CH-π interactions.Chemical science · 2024Article
- Bioinspired Binding and Conversion of Linear Monoterpenes by Polyaromatic Coordination Capsules.ACS organic & inorganic Au · 2024Article
- Diastereoselective Self-Assembly of Low-Symmetry PdAngewandte Chemie (International ed. in English) · 2023Article
- A Porous Polyaromatic Solid for Vapor Adsorption of Xylene with High Efficiency, Selectivity, and Reusability.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- CH-π Multi-Interaction-Driven Recognition and Isolation of Planar Compounds in a Spheroidal Polyaromatic Cavity.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Pseudo-heterolepticity in Low-Symmetry Metal-Organic Cages.Angewandte Chemie (International ed. in English) · 2022Article
- Selective separation of planar and non-planar hydrocarbons using an aqueous PdChemical science · 2022Article
- Adaptive coordination assemblies based on a flexible tetraazacyclododecane ligand for promoting carbon dioxide fixation.Chemical science · 2022Article
- Caged bulky organic dyes in a polyaromatic framework and their spectroscopic peculiarities.Chemical science · 2022Article
Corrections and comments
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Authors and funding
6 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Cyclic monoterpenes (CMTs) are intractable natural products with high volatility and strong odors so that there has been no molecular receptor capable of selectively and tightly trapping CMTs in both solution and the solid state. We herein report that a polyaromatic capsule acts as a functional nanoflask for CMTs with the following five features: (i) the capsule can selectively bind menthone from mixtures with other saturated CMTs in water. In contrast, (ii) treatment of the capsule with mixtures of menthone and π-conjugated CMTs gives rise to ternary host-guest complexes with high pair-selectivity. Notably, (iii) the encapsulated menthone displays unusual isomerization from a typical chair conformer to otherwise unstable conformers upon heating. (iv) The selective binding of volatilized CMTs is demonstrated by the capsule even in the solid state at atmospheric pressure. Furthermore, (v) the volatilities of CMTs are significantly suppressed at elevated temperatures by the capsule upon encapsulation in solution as well as in the solid state.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.