ArticlePolymers2021
Tin Complexes of 4-(Benzylideneamino)benzenesulfonamide: Synthesis, Structure Elucidation and Their Efficiency as PVC Photostabilizers.
Article in Polymers, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed, 15 citations in OpenAlex.
- Investigation of Cinnamic Acid Derivatives as Alternative Plasticizers for Improved Ductility of Polyvinyl Chloride Films.Polymers · 2023Article
- Enhancement of Photostabilization of Poly(Vinyl Chloride) in the Presence of Tin-Cephalexin Complexes.Polymers · 2023Article
- Article
- Synthesis and Application of Levofloxacin-Tin Complexes as New Photostabilizers for Polyvinyl Chloride.Polymers · 2022Article
- Synthesis of New Norfloxacin-Tin Complexes to Mitigate the Effect of Ultraviolet-Visible Irradiation in Polyvinyl Chloride Films.Polymers · 2022Article
- Review
- Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation.Polymers · 2021Article
- FTIR, Weight, and Surface Morphology of Poly(vinyl chloride) Doped with Tin Complexes Containing Aromatic and Heterocyclic Moieties.Polymers · 2021Article
Corrections and comments
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Authors and funding
5 authors at 4 institutions in 3 countries.
Funding
Abstract
Poly(vinyl chloride) (PVC) suffers from photo-oxidation and photodegradation when exposed to harsh conditions. Application of PVC thus relies on the development of ever more efficient photostabilizers. The current research reports the synthesis of new complexes of tin and their assessment as poly(vinyl chloride) photostabilizers. The three new complexes were obtained in high yields from reaction of 4-(benzylideneamino)benzenesulfonamide and tin chlorides. Their structures were elucidated using different tools. The complexes were mixed with poly(vinyl chloride) at a very low concentration and thin films were made from the blends. The effectiveness of the tin complexes as photostabilizers has been established using a variety of methods. The new tin complexes led to a decrease in weight loss, formation of small residues, molecular weight depression, and surface alteration of poly(vinyl chloride) after irradiation. The additives act by absorption of ultraviolet light, removal the active chlorine produced through a dehydrochlorination process, decomposition of peroxides, and coordination with the polymeric chains. The triphenyltin complex showed the greatest stabilizing effect against PVC photodegradation as a result of its high aromaticity.
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Registered trials
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